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Liquid crystalline elastomers as artificial muscles
Open accessAbstract
New nematic co-elastomers were synthesized which consist of a combination of nematic side- and main-chain polymers and where the liquid crystalline main-chain polymer can be considered as a macromolecular crosslinking component. By applying a mechanical field during the crosslinking process, the director of the nematic phase becomes macroscopically uniformly aligned and liquid-single-crystal elastomers were obtained. Within a narrow temperature regime, these networks can change their shape in one dimension by a factor > 3 and considerably improve the ability of being used as artificial muscles or mechanical actuators compared to the well known nematic side-chain elastomers. Networks having a non-ordered polydomain structure exhibit “soft (or semi-soft) elasticity” which is not only determined by a director reorientation process. Obviously, hairpin conformations within the main-chain segments contribute to this effect.
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Cited by
Soft Actuators for Small-Scale Robotics
Hines, L., Petersen, K., Lum, G. Z., & Sitti, M. (2017) · Advanced Materials · doi:10.1002/adma.201603483 · Cited by 1,337
3D printing of liquid crystal elastomeric actuators with spatially programed nematic order
Kotikian, A., Truby, R. L., Boley, J. W., White, T. J., & Lewis, J. A. (2018) · Advanced Materials · doi:10.1002/adma.201706164 · Cited by 768
Four-dimensional printing of liquid crystal elastomers
Ambulo, C. P., Burroughs, J. J., Boothby, J. M., Kim, H., Shankar, M. R., & Ware, T. H. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b11851 · Cited by 508
Thermally-induced two-way shape memory polymers: Mechanisms, structures, and applications
Zare, M., Prabhakaran, M. P., Parvin, N., & Ramakrishna, S. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.05.167 · Cited by 330
Carrico, J. D., Tyler, T., & Leang, K. K. (2017) · International Journal of Smart and Nano Materials · doi:10.1080/19475411.2018.1438534 · Cited by 78
Metadata
- Authors
- Wermter, H., & Finkelmann, H.
- Venue
- e-Polymers
- Publisher
- Walter de Gruyter GmbH
- Published
- 2001-12-01
- Volume
- 1
- Issue
- 1
- ISSN
- 1618-7229 (ISSN-L)
- 2197-4586
- OpenAlex
- W2085587884
- Cited by
- 219
- References
- 0
- FWCI
- 2.28
- Type
- journal article
- Language
- en
- Open access
- bronze
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