Chromatographic analysis of bio-oil formed in fast pyrolysis of lignocellulosic biomass
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Abstract Fast pyrolysis of lignocellulosic biomass is one of the most promising methods of the production of renewable fuels. However, an optimization of the conditions of bio-oil production is not possible without comprehensive analysis of the composition of formed products. There are several methods for the determination of distribution of products formed during thermal decomposition of biomass with chromatography being the most versatile among them. Although, due to the complex structure of bio-oil (presence of hundreds chemical compounds with different chemical character), an interpretation of the obtained chromatograms is not an easy task. Therefore, the aim of this work is to present an application of different chromatographic methods to the analysis of the composition of the mixture of products formed in high temperature decomposition of lignocellulosic feedstock. It includes pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), two dimensional gas (GC x GC) or liquid chromatography (LC x LC) and initial fractionation of bio-oil components. Moreover, the problems connected with the analysis of bio-oils formed with the use of various fast pyrolysis reactors and capabilities of multivariate analysis are discussed.
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Py-GC-MS does not allow for the aggregation of formulated mixtures of reaction components, which are only collected for a short time in the adsorption column before being passed to the gas chromatograph for analysis.
“Furthermore, Py-GC-MS does not allow for the aggregation of formulated mixtures of reaction components, which are only collected for a short time in the adsorption column before being passed to the gas chromatograph for analysis [72].”
From Thermal Analysis Technologies for Biomass Feedstocks: A State-of-the-Art Review (2021) · cites this paper as [72]
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- Authors
- Grams, J.
- Affiliations
- Lodz University of Technology (PL)
- Corresponding author
- Grams, Jacek
- ORCID
- Grams, Jacek
- Venue
- Reviews in Analytical Chemistry
- Publisher
- Walter de Gruyter GmbH
- Published
- 2020-01-01
- Volume
- 39
- Issue
- 1
- Pages
- 65-77
- ISSN
- 0793-0135 (ISSN-L)
- 2191-0189
- OpenAlex
- W3083964862
- Cited by
- 17
- References
- 72
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 2 · 2023: 4 · 2022: 4 · 2021: 2
- FWCI
- 0.79
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Reviews in Analytical Chemistry (publishedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Keywords
- fast pyrolysis, bio-oil, lignocellulosic biomass, pyrolysis product composition, pyrolysis-GC/MS, two-dimensional gas chromatography, two-dimensional liquid chromatography, bio-oil fractionation, multivariate analysis, renewable fuels
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