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Single-phase high-entropy alloys – an overview
Open accessAbstract
The term “high-entropy alloys (HEAs)” first appeared about 10 years ago defining alloys composed of n=5–13 principal elements with concentrations of approximately 100/n at.% each. Since then many equiatomic (or near equiatomic) single- and multi-phase multicomponent alloys were developed, which are reported for a combination of tunable properties: high hardness, strength and ductility, oxidation and wear resistance, magnetism, etc. In our paper, we focus on probably single-phase HEAs (solid solutions) out of all HEAs studied so far, discuss ways of their prediction, mechanical properties. In contrast to classical multielement/multiphase alloys, only single-phase multielement alloys (solid solutions) represent the basic concept underlying HEAs as mixing-entropy stabilized homogenous materials. The literature overview is complemented by own studies demonstrating that the alloys CrFeCoNi, CrFeCoNiAl 0.3 and PdFeCoNi homogenized at 1300 and 1100°C, respectively, for 1 week are not single-phase HEAs, but a coherent mixture of two solid solutions.
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Cites
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys
Guo, S., Ng, C., Lu, J., & Liu, C. T. (2011) · Journal of Applied Physics · doi:10.1063/1.3587228 · Cited by 2,911
Cited by
A critical review of high entropy alloys and related concepts
Miracle, D. B., & Senkov, O. N. (2017) · Acta Materialia · doi:10.1016/j.actamat.2016.08.081 · Cited by 8,973
High-entropy energy materials: challenges and new opportunities
Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963
Jo, Y. H., Jung, S., Choi, W. M., Sohn, S. S., Kim, H. S., Lee, B. J., Kim, N. J., & Lee, S. (2017) · Nature Communications · doi:10.1038/ncomms15719 · Cited by 470
Accelerated exploration of multi-principal element alloys for structural applications
Senkov, O. N., Miller, J. D., Miracle, D. B., & Woodward, C. (2015) · Calphad · doi:10.1016/j.calphad.2015.04.009 · Cited by 275
Sc–Zr–Nb–Rh–Pd and Sc–Zr–Nb–Ta–Rh–Pd High-Entropy Alloy Superconductors on a CsCl-Type Lattice
Stolze, K., Tao, J., von Rohr, F. O., Kong, T., & Cava, R. J. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b04578 · Cited by 122
Metadata
- Authors
- Kozak, R., Sologubenko, A., & Steurer, W.
- Venue
- Zeitschrift für Kristallographie - Crystalline Materials
- Publisher
- Walter de Gruyter GmbH
- Published
- 2014-10-09
- Volume
- 230
- Issue
- 1
- Pages
- 55-68
- ISSN
- 2194-4946 (ISSN-L)
- 2196-7105
- OpenAlex
- W2063590593
- Cited by
- 187
- References
- 1
- FWCI
- 16.36
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Kozak, R., Sologubenko, A., & Steurer, W. (2015). Single-phase high-entropy alloys – an overview. Zeitschrift für Kristallographie - Crystalline Materials. https://doi.org/10.1515/zkri-2014-1739
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