Über die Umsetzung von Polysulfiden mit Stickstoffmonoxid in nichtwäßrigen Lösungsmitteln — Nitrosodisulfide / The Reaction of Polysulfides with Nitrogen Monoxide in Non-Aqueous Solvents — Nitrosodisulfides
Open accessAbstract
Abstract Polysulfides dissolved in non-aqueous solvents react under anaerobic conditions with nitric oxide to yield solutions of nitrosodisulfides. Through the action of NO upon (PNP)2S12 1 [P = P(C6H5)3] in acetone a stable compound PNP · SSNO 2 could be obtained. 2 proved to be identical with a red PNP-salt which had been isolated as a product of the reaction of PNP·NO2 with sulfur in acetone, hitherto taken for PNP · SSNO2. Clearly the product 3 of the action of triphenylphosphane upon 2 has to be regarded as PNP·SNO.
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Taken together, nitrite reacts with S8 and, seemingly less efficiently, with polysulfides in non-aqueous polar solvents to form products including SSNO-.
“Taken together, nitrite reacts with S8 and, seemingly less efficiently, with polysulfides in non-aqueous polar solvents leading to the formation of similar products as observed previously in the reaction of NO with sulfide [69], and nitrosothiols with thiols [70], and with sulfide [19,71] including SSNO -.”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [69]
The NO-containing yellow compound formed from nitrite and S8 is assigned to be nitrosopersulfide, SSNO-.
“Based on Seel's earlier findings [58,68,69] we assign this product to be nitrosopersulfide, SSNO - [19].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [69]
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Research works printed but not linked: 7
- F. Seel, H.-J. Güttier und A. Wieckowski. Pure Appl. Chem. 49, 45 (1977), vgl. auch hier angegebene Lite- ratur.
- J. Bojes, T. Chivers, W. G. Laidlaw und M. Trisc, J. Am. Chem. Soc. 104, 4837 (1982).
- F. Seel, Chimia 37, 301 (1983);
- Stud. Inorg. Chem. 5, 55 (1984).
- G. C. Levy und R. L. Lichter, "Nitrogen-15 Nuclear Magnetic Spectroscopy", J. Wiley, New York 1979.
- F. Seel. Z. Anorg. Allg. Chem. 250, 331 (1943).
- F. Seel und H.-J. Güttier, Angew. Chem. 85, 416 (1973); Int. Ed. Engl. 12, 421 (1973).
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- Authors
- Seel, F., & Wagner, M.
- Affiliations
- Saarland University (DE)
- Venue
- Zeitschrift für Naturforschung B
- Publisher
- Walter de Gruyter GmbH
- Published
- 1985-06-01
- Volume
- 40
- Issue
- 6
- Pages
- 762-764
- ISSN
- 0044-3174 (ISSN-L)
- 1865-7117
- 0932-0776
- OpenAlex
- W2275214527
- Cited by
- 29
- References
- 4
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 1 · 2023: 4 · 2022: 1 · 2020: 1 · 2019: 3 · 2018: 1 · 2017: 3 · 2016: 3 · 2015: 1 · 2014: 3
- FWCI
- 0.99
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Zeitschrift für Naturforschung B (publishedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Reactivity of Sulfur-Containing Compounds
- Physical Sciences › Chemistry › Organic Chemistry › Phosphorus compounds and reactions
- Keywords
- polysulfides, nitric oxide, non-aqueous solvents, triphenylphosphine, acetone
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