Nonlinear sorption and nonequilibrium solute transport in aggregated porous media: experiments, process identification and modeling
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Other studies reported disparities between column and batch methods.
“However, other investigations have reported disparities between the two methods”
From Column versus batch methods for measuring PFOS and PFOA sorption to geomedia (2021) · cites this paper as Fesch et al., 1998
Prior studies observed good agreement between adsorption isotherms from elution-front integration and batch experiments, and between elution-front integration and multi-C0 column experiments, when equilibrium sorption conditions were ensured.
“Prior studies have observed good agreement between adsorption isotherms determined from elution-front integration and batch experiments (Burgisser et al., 1993) and from elution-front integration and multi-C0 column experiments (Fesch et al., 1998; Metzelder et al., 2018) when equilibrium sorption conditions were ensured.”
From Column versus batch methods for measuring PFOS and PFOA sorption to geomedia (2021) · cites this paper as Fesch et al., 1998
Fesch et al. (1998) did not observe good agreement between sorption isotherms from elution-front integration and multiple-C0 column experiments when the column experiments employed a pore-water velocity too high for equilibrium conditions.
“However, Fesch et al. (1998) did not observe good agreement between sorption isotherms determined from elution-front integration and multiple-C0 column experiments when the column experiments employed a pore-water velocity that was too high for equilibrium conditions to be established.”
From Column versus batch methods for measuring PFOS and PFOA sorption to geomedia (2021) · cites this paper as Fesch et al., 1998
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Sorption isotherms: A review on physical bases, modeling and measurement
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“The spatial chemical heterogeneities of the medium have also been invoked (Chrysikopoulos et al., 1990; Brusseau and Zachara, 1993; Wise, 1993; Fesch et al., 1998), but they can be neglected compared with the heterogeneity of the pore water velocities (Brusseau and Zachara, 1993; Johnson et al.”
BackgroundGroundwater quality: remediation and protection
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“Both kinetic sorption and retarded nonlinear intra-particle diffusion (Fesch et al., 1998) may be causing nonequilibrium effects in TNT transport in soils.”
BackgroundColumn versus batch methods for measuring PFOS and PFOA sorption to geomedia
Van Glubt, S., Brusseau, M. L., Yan, N., Huang, D., Khan, N., & Carroll, K. C. (2021) · Environmental Pollution · doi:10.1016/j.envpol.2020.115917 · Cited by 87 · see citing works
“However, other investigations have reported disparities between the two methods (e.g., Celorie et al., 1989; Fesch et al., 1998; Maraqa et al., 1998; Aly et al., 2018).”
BackgroundResultBi, E., Schmidt, T. C., & Haderlein, S. B. (2006) · Environmental Science & Technology · doi:10.1021/es060470e · Cited by 82 · see citing works
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“…experiments, there could also be an increase in surface area resulting from the disaggregation of clusters during shaking and moreover, the pesticide–substrate solution is continuously shaken, which improves contact between pesticide and substrate, which could enhance sorption (Fesch et al., 1998).”
BackgroundThe Penetration Processes of Red Mud Filtrate in a Porous Medium by Seepage
Bai, B., Wang, J., Zhai, Z., & Xu, T. (2017) · Transport in Porous Media · doi:10.1007/s11242-017-0829-9 · Cited by 60 · see citing works
“Fesch et al. (1998) investigated the combined effects of nonlinear sorption, non-equilibrium mass transfer, and sorption site distribution on the transport of organic contaminants in porous media containing aggregates of clayminerals and organicmatter as sorbents.”
BackgroundNew Analytical Model for Cumulative Infiltration into Dual-Permeability Soils
Lassabatère, L., Yılmaz, D., Peyrard, X., Peyneau, P., Lenoir, T., Šimůnek, J., & Angulo-Jaramillo, R. (2014) · Vadose Zone Journal · doi:10.2136/vzj2013.10.0181 · Cited by 59 · see citing works
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Sorption of pharmaceutically active compounds to soils: a review
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“Other categories include review papers (148), risk assessment (97), remediation (281), toxicity (98), plant uptake (32), and metabolites (99).”
BackgroundSlow advection and diffusion through low permeability inclusions
Guswa, A. J., & Freyberg, D. L. (2000) · Journal of Contaminant Hydrology · doi:10.1016/s0169-7722(00)00136-4 · Cited by 42 · see citing works
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Sorption of phenols from water in column systems using surfactant-modified montmorillonite
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Hollenbeck, K. J., Harvey, C. F., Haggerty, R. D., & Werth, C. J. (1999) · Journal of Contaminant Hydrology · doi:10.1016/s0169-7722(98)00165-x · Cited by 37 · see citing works
“The piece-wise linear distribution model gives us the flexibility to approximate many true Žrate distributions, but it does not in itself represent physical process knowledge for that Ž ..perspective, the reader is directed to the extensive article by Fesch et al. 1998 .”
MethodThe boundary filtration effect of reed-dominated ecotones under water level fluctuations
Wang, W., & Yin, C. (2007) · Wetlands Ecology and Management · doi:10.1007/s11273-007-9057-3 · Cited by 36 · see citing works
“In fact, when water enters the boundary zones, it will move quickly through the root channels into deeper and farther distances (Gaiser 1952; Devitt and Smith 2002) which depend partially on the natural water contents (Fesch et al. 1998a) of wetland soils and subsurface water depths.”
Tertre, E., Hubert, F., Bruzac, S., Pacreau, M., Ferrage, E., & Prêt, D. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.02.028 · Cited by 35 · see citing works
Effect of water content on solute transport in a porous medium containing reactive micro-aggregates
Fesch, C., Lehmann, P., Haderlein, S. B., Hinz, C., Schwarzenbach, R. P., & Flühler, H. (1998) · Journal of Contaminant Hydrology · doi:10.1016/s0169-7722(98)00071-0 · Cited by 35 · see citing works
Practical issues relating to soil column chromatography for sorption parameter determination
Bi, E., Schmidt, T. C., & Haderlein, S. B. (2010) · Chemosphere · doi:10.1016/j.chemosphere.2010.05.006 · Cited by 34 · see citing works
Qin, Q., Chen, X., & Zhuang, J. (2017) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2017.04.148 · Cited by 34 · see citing works
“Fesch et al. (1998) found that the presence of such immobile regions, though they accounted for a very small fraction, might affect the transport of sorbed solutes if sorption siteswere located therein.”
BackgroundSimulation of nonlinear sorption of N-heterocyclic organic contaminates in soil columns
Bi, E., Zhang, L., Schmidt, T. C., & Haderlein, S. B. (2009) · Journal of Contaminant Hydrology · doi:10.1016/j.jconhyd.2009.04.001 · Cited by 31 · see citing works
Beltman, W. H. J., Boesten, J. J. T. I., & van der Zee, S. E. A. T. M. (2008) · Water Resources Research · doi:10.1029/2007wr006436 · Cited by 31 · see citing works
“…by un [van Duijn et al., 1997], (2) the dispersion term in equation (10) can be ignored because nonlinear sorption dominates pulse spreading at large times and pore scale dispersion is of lesser importance [Fesch et al., 1998; Bosma et al., 1996], and (3) that no transformation is assumed to occur.”
BackgroundRhamnolipid Transport in Biochar-Amended Agricultural Soil
Vu, K. A., Tawfiq, K. S., & Chen, G. (2015) · Water Air & Soil Pollution · doi:10.1007/s11270-015-2497-0 · Cited by 27 · see citing works
“The adsorption isotherms simulated from transport breakthrough curves should follow Langmuir adsorption isotherms (Fesch et al. 1998): S ¼ αKCe 1þ KCe ð14Þ where S is the adsorbed rhamnolipid in the soil; α is the mass of rhamnolipid required to completely cover a unit mass of soil surface; Ce is…”
BackgroundSorption Behavior of Phthalic Acid Esters on Reference Soils Evaluated by Soil Column Chromatography
Li, B., Qian, Y., Bi, E., Chen, H., & Schmidt, T. C. (2010) · CLEAN - Soil Air Water · doi:10.1002/clen.200900241 · Cited by 26 · see citing works
Agricultural Drainage Filters. II. Phosphorus Retention and Release at Different Flow Rates
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BackgroundSorption of Heterocyclic Organic Compounds to Multiwalled Carbon Nanotubes
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Numerical analysis for characterizing the sorption/desorption of cesium in crushed granite
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“Furthermore, a two-region model was developed and proposed to simulate the retarded transport of organic contaminants in porous media containing aggregates of clay minerals and organic matter as sorbents, which was incorporated with nonlinear sorption and intra-aggregate diffusion [14].”
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“It has already been shown that the assumption of a linear gradient may not always be appropriate (Fesch et al., 1998; Hills, 1986; Wehrer and Totsche, 2008; Young and Ball, 1995).”
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Mountain Streams—Modeling Hydraulics and Substance Transport
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“This theory underlies most applications, notably for sorption parameter identification (e.g. Bajracharya and Barry, 1997; Fesch et al., 1998), although it can give rise to difficulties (Pinheiro and Bates, 2000; Seber and Wild, 1989).”
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“Such physical non-equilibrium also gives rise to an early breakthrough phenomenon, and affects both preservative and sorbing contaminants (Brusseau, 1995; Fesch et al., 1998; Pignatello & Xing, 1996).”
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Retardation of Nonlinearly Sorbed Solutes in Porous Media
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“They used the area above the sorption front of the breakthrough curve to calculate the sorbed mass of the solute multiplied by the test flow rate (Buergisser et al. 1993; Fesch et al. 1998).”
BackgroundMethodResultInfluentialBeyond the isotherm: Limits in prediction of PFAS breakthrough behaviour in continuous flow column
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- Authors
- Fesch, C., Simon, W., Haderlein, S. B., Reichert*, P., & Schwarzenbach, R. P.
- Affiliations
- Swiss Federal Institute of Aquatic Science and Technology (CH)
- Corresponding author
- Haderlein, Stefan B
- ORCID
- Haderlein, Stefan B
- Venue
- Journal of Contaminant Hydrology
- Publisher
- Elsevier BV
- Published
- 1998-06
- Volume
- 31
- Issue
- 3-4
- Pages
- 373-407
- ISSN
- 0169-7722 (ISSN-L)
- OpenAlex
- W2145639849
- Cited by
- 86
- References
- 74
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 3 · 2022: 3 · 2021: 3 · 2020: 3 · 2018: 1 · 2017: 5 · 2016: 7 · 2015: 2 · 2014: 7 · 2013: 3 · 2012: 2
- FWCI
- 4.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Contaminant Hydrology (publishedVersion)
- DORA Eawag (Swiss Federal Institute of Aquatic Science and Technology (Eawag)) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › Groundwater flow and contamination studies
- Physical Sciences › Engineering › Civil and Structural Engineering › Soil and Unsaturated Flow
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- nonlinear sorption, solute transport, clay minerals, organic matter, organic pollutants, breakthrough curves, mine tailings, two-region model, process identification, miscible displacement, rate-limited mass transfer
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