The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Aqueous Pyrite Oxidation and the Consequent Formation of Secondary Iron Minerals
Abstract
The oxidation of pyrite in aqueous systems is a complex biogeochemical process involving several redox reactions and microbial catalysis. This paper reviews the kinetic data on pyrite oxidation, compares available data on the inorganic vs. microbial oxidative mechanisms and describes the occurrence of mineral products resulting from pyrite oxidation. Although oxygen is the overall oxidant, kinetic data suggests that ferric iron is the direct oxidant in acid systems and that temperature, pH, surface area, and the presence of iron and sulfur-oxidizing bacteria can greatly affect the rate of reaction. The vast amount of literature on the microbial and geochemical investigations on this subject have limited usefulness for understanding natural systems. Additional research is needed on the hydrologic, geologic and microbiologic characteristics of field sites where oxidation occurs. The acid water resulting from pyrite oxidation may precipitate a large suite of soluble and insoluble iron minerals depending on pH, degree of oxidation, moisture content, and solution composition.
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Brock, T. D., & Gustafson, J. (1976) · Applied and Environmental Microbiology · doi:10.1128/aem.32.4.567-571.1976 · Cited by 290
Nitrogen Fixation by Thiobacillus ferrooxidans
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Cited by
Kinetics of Mineral Dissolution
Brantley, S. L. (2008) · Kinetics of Water-Rock Interaction · doi:10.1007/978-0-387-73563-4_5 · Cited by 349
Metal-sulfate Salts from Sulfide Mineral Oxidation
Jambor, J. L., Nordstrom, D. K., & Alpers, C. N. (2000) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2000.40.6 · Cited by 340
Pyrite oxidation in carbonate-buffered solution: 1. Experimental kinetics
Nicholson, R. V., Gillham, R. W., & Reardon, E. J. (1988) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(88)90262-1 · Cited by 305
Acute salt marsh dieback in the Mississippi River deltaic plain: a drought‐induced phenomenon?
McKee, K. L., Mendelssohn, I. A., & D. Materne, M. (2004) · Global Ecology and Biogeography · doi:10.1111/j.1466-882x.2004.00075.x · Cited by 245
Geomicrobiology of pyrite (FeS2) dissolution: Case study at Iron Mountain, California
Katrina J. Edwards, B. M. G. (1999) · Geomicrobiology Journal · doi:10.1080/014904599270668 · Cited by 175
Metadata
- Authors
- Kirk Nordstrom, D.
- Venue
- SSSA Special Publications
- Publisher
- Wiley
- Published
- 1982-01
- Pages
- 37-56
- ISSN
- 0081-1904 (ISSN-L)
- 2165-9826
- OpenAlex
- W2225748160
- Cited by
- 533
- References
- 28
- Type
- other
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.