Cited by 131

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Ferrates (iron(VI) and iron(V)): Environmentally friendly oxidants and disinfectants

Sharma, Virender K., Kazama, Futaba, Jiangyong, Hu, Ray, Ajay K.·2005·Journal of Water and Health

Abstract

Iron(VI) and iron(V), known as ferrates, are powerful oxidants and their reactions with pollutants are typically fast with the formation of non-toxic by-products. Oxidations performed by Fe(VI) and Fe(V) show pH dependence; faster rates are observed at lower pH. Fe(VI) shows excellent disinfectant properties and can inactivate a wide variety of microorganisms at low Fe(VI) doses. Fe(VI) also possesses efficient coagulation properties and enhanced coagulation can also be achieved using Fe(VI) as a preoxidant. The reactivity of Fe(V) with pollutants is approximately 3–5 orders of magnitude faster than that of Fe(VI). Fe(V) can thus be used to oxidize pollutants and inactivate microorganisms that have resistance to Fe(VI). The final product of Fe(VI) and Fe(V) reduction is Fe(III), a non-toxic compound. Moreover, treatments by Fe(VI) do not give any mutagenic/carcinogenic by-products, which make ferrates environmentally friendly ions. This paper reviews the potential role of iron(VI) and iron(V) as oxidants and disinfectants in water and wastewater treatment processes. Examples are given to demonstrate the multifunctional properties of ferrates to purify water and wastewater

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Crossref · 10.2166/wh.2005.0005

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2 of 2 references verified0 citation errors · 0 not checkable

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  • Ferrate anions are very suitable for use in drinking water treatment.

    “Ferrate anions are very suitable for use in drinking water treatment.”
  • Traditional chlorination treatment processes have challenges including high dosages and long contact time, which lead to the formation of carcinogenic disinfection byproducts (DBPs) such as trichloromethanes.

    “Challenges with the use of traditional chlorination treatment processes include high dosages and long contact time, which lead to the formation of carcinogenic disinfection byproducts (DBPs) such as trichloromethanes 1 .”
  • The wet chemical method for ferrate production has a relatively low yield (10-15%) and requires additional reagents and further steps to purify and separate the desired product, leading to high costs.

    “This process has a is relatively low yield (10-15%) and additional reagents and further steps are required to further purify and separate the desired product, leading to high costs 1 .”
  • Ferrates have been shown to be very effective in the removal of Escherichia Coli, fecal coliform, sulphur and nitrogen containing contaminants and toxins.

    “In particular, they have been shown to be very effective in the removal of Escherichia Coli, fecal coliform, sulphur and nitrogen containing contaminants 1 and toxins 2 .”
  • Ozonation is ineffective in alkaline conditions and may result in the formation of carcinogenic bromates when bromides ions are present in water.

    “Ozonation is an alternative disinfection method, but it is ineffective in alkaline conditions and may result in the formation of carcinogenic bromates when bromides ions are present in water 1 .”

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Metadata

Authors
Sharma, V. K., Kazama, F., Jiangyong, H., & Ray, A. K.
Venue
Journal of Water and Health
Published
2005-03-01
Volume
3
Issue
1
Pages
45-58
ISSN
  • 1477-8920
  • 1996-7829
Cited by
131
References
2
Language
en

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