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The binary system H 2 O-CO 2 at high temperatures and pressures
Open accessAbstract
The system water-carbon dioxide was studied to pressures of 1,600 bars and at temperatures of 110 degrees C to 350 degrees C. Preliminary work was done also up to pressures of 3,000 bars. The critical curve of the system trends toward higher pressures at lower temperatures and departs strongly from the critical point of pure water. At low pressures the CO ~2~ rich phase is the light phase, but at higher pressures this phase is the denser fluid phase. In a natural system of H ~2~ O-CO ~2~ complete miscibility will not exist below 265 degrees C; at higher temperatures a completely mixed super-critical fluid may exist, but at lower temperatures this fluid will segregate into two fluid phases.
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Citations
Cited by
Spycher, N., Pruess, K., & Ennis-King, J. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(03)00273-4 · Cited by 991
Diamond, L. W., & Akinfiev, N. N. (2003) · Fluid Phase Equilibria · doi:10.1016/s0378-3812(03)00041-4 · Cited by 578
Sheppard, S. M. F., & Schwarcz, H. P. (1970) · Contributions to Mineralogy and Petrology · doi:10.1007/bf00373200 · Cited by 446
Spycher, N., & Pruess, K. (2010) · Transport in Porous Media · doi:10.1007/s11242-009-9425-y · Cited by 315
Carbon Dioxide in Biomass Processing: Contributions to the Green Biorefinery Concept
Morais, A. R. C., da Costa Lopes, A. M., & Bogel-Łukasik, R. (2015) · Chemical Reviews · doi:10.1021/cr500330z · Cited by 296
Metadata
- Authors
- Takenouchi, S., & Kennedy, G. C.
- Venue
- American Journal of Science
- Publisher
- American Journal of Science (AJS)
- Published
- 1964-11-01
- Volume
- 262
- Issue
- 9
- Pages
- 1055-1074
- ISSN
- 0002-9599 (ISSN-L)
- OpenAlex
- W2013080982
- Cited by
- 610
- References
- 0
- FWCI
- 2.77
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Takenouchi, S., & Kennedy, G. C. (1964). The binary system H 2 O-CO 2 at high temperatures and pressures. American Journal of Science. https://doi.org/10.2475/ajs.262.9.1055
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