Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions; IV, Retrieval of rate constants and activation parameters for the hydrolysis of pyroxene, wollastonite, olivine, andalusite, quartz, and nepheline
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Ferromagnesian silicates, typical of Martian igneous rocks, are dissolved by acidic water to produce cations including Fe2+, Mg2+, Ca2+, K+, Na+, and silica in roughly stoichiometric proportion to the mineral composition under low-oxygen conditions.
“Ferromagnesian silicates, typical of Martian igneous rocks, are dissolved by such acidic water to produce curious including Fe 2+, Mg •+, Ca 2+, K +, Na +, and silica in roughly stoichiometric proportion to the mineral composition under low-oxygen conditions, according to laboratory experiments [Murphy and Helgeson, 1989; Burns, 1993].”
From A chemical model for evaporites on early Mars: Possible sedimentary tracers of the early climate and implications for exploration (1999) · cites this paper as Murphy and Helgeson, 1989
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Palandri, J. L., & Kharaka, Y. K. (2004) · Open-File Report · doi:10.3133/ofr20041068 · Cited by 1,352 · see citing works
Olivine dissolution rates: A critical review
Oelkers, E. H., Declercq, J., Saldi, G. D., Gislason, S. R., & Schott, J. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.10.008 · Cited by 296 · see citing works
Catling, D. C. (1999) · Journal of Geophysical Research: Planets · doi:10.1029/1998je001020 · Cited by 148 · see citing works
- Authors
- Murphy, W. M., & Helgeson, H. C.
- ORCID
- Murphy, W. M.
- Venue
- American Journal of Science
- Publisher
- American Journal of Science (AJS)
- Published
- 1989-01-01
- Volume
- 289
- Issue
- 1
- Pages
- 17-101
- ISSN
- 0002-9599 (ISSN-L)
- OpenAlex
- W2331820982
- Cited by
- 95
- References
- 0
- Citations by year
- 2025: 1 · 2023: 1 · 2022: 2 · 2019: 3 · 2018: 2 · 2017: 1 · 2016: 4 · 2015: 3 · 2014: 3 · 2013: 3 · 2012: 2
- FWCI
- 4.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- American Journal of Science (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- mineral dissolution kinetics, rate constants, activation parameters, wollastonite, olivine, andalusite, quartz, nepheline, mineral-water reactions, thermodynamic constraints
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