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Cited by 22Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research

Acetonitrile-based electrolytes for lithium-ion battery application

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Hilbig, Peter, Ibing, Lukas, Streipert, Benjamin, Wagner, Ralf, Winter, Martin, Cekic-Laskovic, Isidora·2018·Current Topics in Electrochemistry
DOI 10.31300/ctec.20.2018.1-13
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Abstract

Compared to the commercially used state-of-the art non-aqueous organic carbonate solvent-based electrolytes, acetonitrile (AN)-based electrolytes have the advantage of enabling higher conductivity and lower viscosity values.The beneficial influence of adding fluoroethylene carbonate (FEC), thus enabling AN compatibility with graphite anodes, in different ratios to AN-based electrolytes represents the main focus of this manuscript.Long-term cycling measurements at 0 °C and 20 °C as well as conductivity and electrochemical stability measurements were performed to identify the optimal AN:FEC ratio.The electrochemical performance as well as the decomposition products were further investigated in graphite/lithium iron phosphate (LFP) cells to validate the applicability in lithium-ion cells.

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  • Acetonitrile is helpful for improving lithium-ion transport properties at low temperature (0 °C) but needs fluoroethylene carbonate as an additive to enable reversible cycling for graphite-anode-based full cells.

    “Hilbig et al. [53] showed similar results, suggesting that AN is helpful for improving lithium-ion transport properties at LT (0 °C) but needs FEC as the additive to enable the reversible cycling for the graphite-anode-based full cells.”

    From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [53]

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Authors
Hilbig, P., Ibing, L., Streipert, B., Wagner, R., Winter, M., & Cekic-Laskovic, I.
Affiliations
  • University of Münster (DE)
  • Forschungszentrum Jülich (DE)
ORCID
Venue
Current Topics in Electrochemistry
Publisher
Research Trends, Ltd.
Published
2018-12-31
Volume
20
Pages
1
ISSN
0972-4443 (ISSN-L)
DOI
10.31300/ctec.20.2018.1-13
OpenAlex
W2912025129
Cited by
22
References
1
Citations by year
2025: 4 · 2024: 3 · 2023: 2 · 2022: 6 · 2021: 3 · 2020: 2 · 2019: 2
FWCI
0.67
Type
journal article
Language
en
Open access
Locations
Current Topics in Electrochemistry (publishedVersion)
Funders
Bundesministerium für Bildung und Forschung
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
  • Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
Keywords
lithium-ion batteries, fluoroethylene carbonate, graphite anode, electrolyte conductivity, electrolyte viscosity, electrochemical stability window, electrolyte decomposition products, LiFePO4 cathode

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