Methanol dynamically activated room-temperature phosphorescence from a twisted 4-bromobiphenyl system
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Crystal engineering is employed widely in developing metal-free room-temperature phosphorescence (RTP) materials, but the weak responsiveness in rigid state and poor selectivity during crystallizat...
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Introduction of the heavy-atom effect (-Br moieties) of open-ring PSP molecules could effectively promote the spin-orbital coupling (SOC) of the system to promote the ISC process, and the spin-orbit matrix elements increase significantly with an increasing number of heavy atom modifications.
“Moreover, introduction of the heavy-atom effect (-Br moieties) of open-ring PSP molecules could effectively promote the spin-orbital coupling (SOC) of the system to promote the ISC process (Table 2), and the spin-orbit matrix elements (<S1|HSO|Tn>) [37] would increase significantly with an increasing number of heavy atomatic modifications.”
From Red-light excited efficient metal-free near-infrared room-temperature phosphorescent films (2022) · cites this paper as [37]
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References 15 · Cited by 50
- Authors
- Yuan, Z., Wang, J., Chen, L., Zou, L., Gong, X., & Ma, X.
- Affiliations
- East China University of Science and Technology (CN)
- Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237
- Venue
- CCS Chemistry
- Publisher
- Chinese Chemical Society
- Published
- 2020-06
- Volume
- 2
- Issue
- 3
- Pages
- 158-167
- ISSN
- 2096-5745 (ISSN-L)
- OpenAlex
- W3010502507
- Cited by
- 50
- References
- 15
- Citations by year
- 2026: 1 · 2025: 5 · 2024: 4 · 2023: 11 · 2022: 11 · 2021: 12 · 2020: 6
- FWCI
- 3.89
- Type
- journal article
- Language
- en
- Open access
- diamond
- doi.org
- Licence
- cc-by-nc
- Locations
- CCS Chemistry (publishedVersion, cc-by-nc)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence Properties of Advanced Materials
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
- Keywords
- room-temperature phosphorescence, methanol activation, crystal engineering
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