The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Development of the inner oxide zone upon steam oxidation of an austenitic stainless steel
Abstract
The oxidation behaviour of TP 347H FG in mixtures of water, oxygen, and hydrogen was investigated in the temperature range 500–700°C for a fixed oxidation time of 336 h. The samples were characterised using reflective light and electron microscopy methods. Thin discontinuous double-layered oxide scales developed during oxidation at 500°C, whereas continuous double-layered oxide scales covered the entire sample surface after oxidation at 600 and 700°C. The major part of the scale grew into the former alloy grains, whereas Fe—Cr spinel grew along the former alloy grain boundaries. TEM and EELS investigations revealed that the part of the scale that grows into the alloy grains consists of particles of Fe—Cr spinel embedded in a metallic Fe—Ni matrix, which indicates that this part of the scale grows by an internal oxidation mechanism. Growth of the internal oxidation zone at high humidity (46%) is not significantly affected by the type of carrier gas used.
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Previous research focused on the initiation/breakaway event indicates a similar microstructure after the onset of breakaway of Fe-based alloys, seemingly independent of the suggested breakaway reaction.
“Previous research, focused on the initiation/breakaway event, indicate a similar microstructure obtained after the onset of breakaway of Fe-based alloys, seemingly independent of suggested breakaway-reaction [8,20,22,29,31].”
From The influence of Nickel on the corrosion protection of FeCrNi alloys after breakaway corrosion at 600 °C (2024) · cites this paper as [31]
Regardless of the environments studied, the oxide scales formed after breakaway have been composed of an outward-growing almost pure Fe oxide and an inward-growing oxide with a more complex microstructure and varying composition.
“Regardless of the environments studied, the oxide scales have been composed of an outward-growing almost pure Fe oxide, and an inward-growing oxide with a more complex microstructure and varying composition.”
From The influence of Nickel on the corrosion protection of FeCrNi alloys after breakaway corrosion at 600 °C (2024) · cites this paper as [31]
Previous studies [24-26,31] indicate that both types of oxides have grown in part by internal oxidation.
“This is in good agreement with previous studies [24-26,31], indicating that both these type of oxides have grown in part by internal oxidation.”
From The influence of Nickel on the corrosion protection of FeCrNi alloys after breakaway corrosion at 600 °C (2024) · cites this paper as [31]
Citations
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Steam oxidation of Super 304H and shot-peened Super 304H
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Understanding the relationship between Si alloying and corrosion performance of ZnAlMg coatingsPreprint
Šefl, V., Švadlena, J., Saarimaa, V., Suárez, L., & Prošek, T. (2026) · SSRN Electronic Journal · doi:10.2139/ssrn.6614770
Metadata
- Authors
- Hansson, A. N., Montgomery, M., & Somers, M. A. J.
- Affiliations
- Ørsted (Denmark) (DK)
- Vattenfall (Denmark) (DK)
- Technical University of Denmark (DK)
- Corresponding author
- Hansson, Anette N.
- Venue
- Materials at High Temperatures
- Publisher
- Informa UK Limited
- Published
- 2009-03
- Volume
- 26
- Issue
- 1
- Pages
- 39-44
- ISSN
- 0960-3409 (ISSN-L)
- 1878-6413
- OpenAlex
- W1988333070
- Cited by
- 11
- References
- 17
- Citations by year
- 2026: 1 · 2024: 2 · 2021: 1 · 2018: 1 · 2014: 1 · 2013: 1 · 2012: 3
- FWCI
- 2.59
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Materials at High Temperatures (publishedVersion)
- Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion)
- Funders
- Vattenfall
- Topics
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Metals and Alloys › Hydrogen embrittlement and corrosion behaviors in metals
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Keywords
- steam oxidation, austenitic stainless steel, internal oxidation, Fe-Cr spinel, carrier gas effects, high-temperature oxidation
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