Cited by 29Asphalt Pavement Performance EvaluationTiO2 Photocatalysis and Solar CellsPolymer Nanocomposites and Properties

The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.

A Study on Modified Bitumen with Metal Doped Nano-TiO2 Pillared Montmorillonite

Open access

Abstract

TiO2 pillared montmorillonite (T/M) modifiers have been studied to alleviate the aging of asphalt pavement and degrade automobile exhaust, but the photocatalytic activity of ordinary TiO2 is not good enough. In this study, in order to improve the photocatalytic performance of T/M, different metal (Ce, Cu, Fe) doped modifiers were prepared based on T/M. Metal doped TiO2 pillared montmorillonite was prepared by the sol-gel method. The modifier was characterized by X-ray diffraction (XRD) and an Ultraviolet visible (UV-Vis) spectrophotometer. The results show that TiO2 with different metal ions successfully entered into the layer of organic montmorillonite (OMMT) to form a pillared structure. Compared with the undoped TiO2 pillared montmorillonite (T/M), the optical absorption edge of the metal doped TiO2 pillared montmorillonite has an obvious red shift. In addition, the influences of the different content of modifiers on the properties of the original bitumen and catalytic capacities for automobile exhaust were also investigated. The results show that Ce doped TiO2 (Ce-T/M) pillared montmorillonite has the best improvement in high temperature performance and ultraviolet (UV) resistance of bitumen. In the experiment of automobile exhaust degradation, the degradation law of NO and HC showed Cu-T/M > Ce-T/M > Fe-T/M > T/M. These three kinds of metal ions can effectively improve the photocatalytic degradation efficiency of T/M.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.3390/ma12121910

Cites

37 of 37 references verified0 citation errors · 0 not checkable

Statistics

Figures

Figure 1 X-ray diffraction (XRD) patterns of MMT and (a) Cu-T/M, (b) Fe-T/M, (c) Ce-T/M with their precursor.
Figure 1 X-ray diffraction (XRD) patterns of MMT and (a) Cu-T/M, (b) Fe-T/M, (c) Ce-T/M with their precursor.CC BY · PubMed Central
Figure 2 UV-Vis spectrum of metal doped TiO2 pillared montmorillonite.
Figure 2 UV-Vis spectrum of metal doped TiO2 pillared montmorillonite.CC BY · PubMed Central
Figure 3 (a) TEM image of Ce-T/M powder and (b) fluorescence microscope (FM) image of 5 wt % Ce-T/M modified bitumen.
Figure 3 (a) TEM image of Ce-T/M powder and (b) fluorescence microscope (FM) image of 5 wt % Ce-T/M modified bitumen.CC BY · PubMed Central
Figure 4 Variation of the G*/sinδ value of (a) Ce-T/M, (b) Cu-T/M, (c) Fe-T/M modified bitumen at different temperatures.
Figure 4 Variation of the G*/sinδ value of (a) Ce-T/M, (b) Cu-T/M, (c) Fe-T/M modified bitumen at different temperatures.CC BY · PubMed Central
Figure 5 Variation of δ value of (a) Ce-T/M, (b) Cu-T/M, and (c) Fe-T/M modified bitumen at different temperatures.
Figure 5 Variation of δ value of (a) Ce-T/M, (b) Cu-T/M, and (c) Fe-T/M modified bitumen at different temperatures.CC BY · PubMed Central
Figure 6 The AI value of (a) Ce-T/M, (b) Cu-T/M, and (c) Fe-T/M modified bitumen after UV aging.
Figure 6 The AI value of (a) Ce-T/M, (b) Cu-T/M, and (c) Fe-T/M modified bitumen after UV aging.CC BY · PubMed Central
Figure 7 Degradation curve of NO by four modified bitumen.
Figure 7 Degradation curve of NO by four modified bitumen.CC BY · PubMed Central
Figure 8 Degradation curve of HC by four modified bitumen.
Figure 8 Degradation curve of HC by four modified bitumen.CC BY · PubMed Central

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 37 references

Cited by

Sorted by citations

See all 29

Metadata

Authors
Jin, J., Chen, B., Liu, L., Liu, R., Qian, G., Wei, H., & Zheng, J.
Affiliations
  • Changsha University of Science and Technology (CN)
  • Central South University (CN)
Corresponding author
  • Jin, Jiao
  • Liu, Ruohua
  • Qian, Guoping
Venue
Materials
Publisher
MDPI AG
Published
2019-06-13
Volume
12
Issue
12
Pages
1910
ISSN
1996-1944 (ISSN-L)
OpenAlex
W2949353791
Cited by
29
References
37
Citations by year
2026: 2 · 2025: 3 · 2024: 2 · 2023: 4 · 2022: 6 · 2021: 8 · 2020: 2 · 2019: 2
FWCI
3.37
Type
journal article
Language
en
Open access
Locations
  • Materials (publishedVersion, cc-by)
  • Europe PMC (PubMed Central) (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
  • National Natural Science Foundation of China (51704040, 51708048)
  • Hunan Provincial Natural Science Foundation of China (2019JJ50663)
  • Open Fund of Key Laboratory of Special Environment Road Engineering of Hunan Province (kfj160501&170502)
  • Key Projects of Hunan Province-Technological Innovation Project in Industry (2016GK2096)
  • Opening Project of Key Laboratory of Road Structure and Materials, Guangxi (2018gxjgclkf001)
Topics
  • Physical Sciences › Engineering › Civil and Structural Engineering › Asphalt Pavement Performance Evaluation
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
Keywords
modified asphalt, metal-doped TiO2, photocatalytic degradation, vehicle emissions, cerium doping, copper doping, iron doping, asphalt aging, UV resistance, high-temperature performance, optical absorption edge red shift, sol-gel synthesis

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: A Study on Modified Bitumen with Metal Doped Nano-TiO2 Pillared Montmorillonite. https://app.cochat.ai/papers/10.3390/ma12121910
The paper
Jin, J., Chen, B., Liu, L., Liu, R., Qian, G., Wei, H., & Zheng, J. (2019). A Study on Modified Bitumen with Metal Doped Nano-TiO2 Pillared Montmorillonite. Materials. https://doi.org/10.3390/ma12121910