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Porphyrins as Catalysts in Scalable Organic Reactions
Open accessAbstract
Catalysis is a topic of continuous interest since it was discovered in chemistry centuries ago. Aiming at the advance of reactions for efficient processes, a number of approaches have been developed over the last 180 years, and more recently, porphyrins occupy an important role in this field. Porphyrins and metalloporphyrins are fascinating compounds which are involved in a number of synthetic transformations of great interest for industry and academy. The aim of this review is to cover the most recent progress in reactions catalysed by porphyrins in scalable procedures, thus presenting the state of the art in reactions of epoxidation, sulfoxidation, oxidation of alcohols to carbonyl compounds and C–H functionalization. In addition, the use of porphyrins as photocatalysts in continuous flow processes is covered.
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Cites
Structure and chemistry of cytochrome p450
Denisov, I. G., Makris, T. M., Sligar, S. G., & Schlichting, I. (2005) · Chemical Reviews · doi:10.1021/cr0307143 · Cited by 2,106
Continuous flow reactors: a perspective
Wiles, C., & Watts, P. (2012) · Green Chem. · doi:10.1039/c1gc16022b · Cited by 626
Semisynthetic Artemisinin, the Chemical Path to Industrial Production
Turconi, J., Griolet, F., Guevel, R., Oddon, G., Villa, R., Geatti, A., Hvala, M., Rossen, K., Göller, R., & Burgard, A. (2014) · Organic Process Research & Development · doi:10.1021/op4003196 · Cited by 228
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Post-synthetic modification of covalent organic frameworks
Segura, J. L., Royuela, S., & Mar Ramos, M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00978c · Cited by 832
Metadata
- Authors
- Barona-Castaño, J., Carmona-Vargas, C., Brocksom, T., & De Oliveira, K.
- Venue
- Molecules
- Publisher
- MDPI AG
- Published
- 2016-03-08
- Volume
- 21
- Issue
- 3
- Pages
- 310
- ISSN
- 1420-3049 (ISSN-L)
- OpenAlex
- W2294827765
- Cited by
- 306
- References
- 3
- FWCI
- 13.53
- Type
- journal article
- Language
- en
- Open access
- gold
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- Barona-Castaño, J., Carmona-Vargas, C., Brocksom, T., & De Oliveira, K. (2016). Porphyrins as Catalysts in Scalable Organic Reactions. Molecules. https://doi.org/10.3390/molecules21030310
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