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Design and Evaluation of a New Natural Multi-Layered Biopolymeric Adsorbent System-Based Chitosan/Cellulosic Nonwoven Material for the Biosorption of Industrial Textile Effluents

EL-Ghoul, Yassine, Ammar, Chiraz, Alminderej, Fahad M., Shafiquzzaman, Md.·2021·Polymers
DOI 10.3390/polym13030322PMC PMC7864031
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Abstract

The adsorption phenomenon using low-cost adsorbents that are abundant in nature is of great interest when the adsorbed capacity is significant. A newly designed natural polyelectrolyte multi-layered (PEM) biopolymeric system-based chitosan/modified chitosan polymer and functionalized cellulosic nonwoven material was prepared and used as an effective adsorbent for Reactive Red 198 (RR198) dye solutions. The bio-sorbent was characterized by FTIR, SEM, and thermal (TGA/DTA) analysis. The swelling behavior was also evaluated, showing the great increase of the hydrophilicity of the prepared adsorbent biopolymer. The effect of various process parameters on the performance of RR198 dye removal such as pH, contact time, temperature, and initial dye concentration was studied. The biopolymeric system has shown good efficiency of adsorption compared to other adsorbents based on chitosan polymer. The highest adsorption capacity was found to be 722.3 mgg−1 at pH = 4 (ambient temperature, time = 120 min and dye concentration = 600 mg L−1). The adsorption process fitted well to both pseudo-second-order kinetics and Freundlich/Temkin adsorption isotherm models. Regarding its low cost, easy preparation, and promising efficient adsorption results, this new concepted multi-layered bio-sorbent could be an effective solution for the treatment of industrial wastewater.

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Metadata

Authors
EL-Ghoul, Y., Ammar, C., Alminderej, F. M., & Shafiquzzaman, M.
Venue
Polymers
Publisher
MDPI AG
Published
2021-01-20
Volume
13
Issue
3
Pages
322
ISSN
2073-4360
DOI
10.3390/polym13030322
PMC
PMC7864031
Cited by
23
References
1
Language
en
Licence
creativecommons.org/licenses/by/4.0/ (vor)
Funders
Qassim University (5656 -cos-2019-2-2-I)

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