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Metal-Organic Frameworks for Sensing Applications in the Gas Phase
Open accessAbstract
Several metal-organic framework (MOF) materials were under investigated to test their applicability as sensor materials for impedimetric gas sensors. The materials were tested in a temperature range of 120 °C - 240 °C with varying concentrations of O2, CO2, C3H8, NO, H2, ethanol and methanol in the gas atmosphere and under different test gas humidity conditions. Different sensor configurations were studied in a frequency range of 1 Hz -1 MHz and time-continuous measurements were performed at 1 Hz. The materials did not show any impedance response to O2, CO2, C3H8, NO, or H2 in the gas atmospheres, although for some materials a significant impedance decrease was induced by a change of the ethanol or methanol concentration in the gas phase. Moreover, pronounced promising and reversible changes in the electric properties of a special MOF material were monitored under varying humidity, with a linear response curve at 120 °C. Further investigations were carried out with differently doped MOF materials of this class, to evaluate the influence of special dopants on the sensor effect.
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Cites
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Cited by
Zhan, W.-W., Kuang, Q., Zhou, J.-Z., Kong, X.-J., Xie, Z.-X., & Zheng, L.-S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja311085e · Cited by 803
MOF positioning technology and device fabrication
Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Yao, M., Tang, W., Wang, G., Nath, B., & Xu, G. (2016) · Advanced Materials · doi:10.1002/adma.201506457 · Cited by 641
Sensors for Volatile Organic Compounds
Khatib, M., & Haick, H. (2022) · ACS Nano · doi:10.1021/acsnano.1c10827 · Cited by 533
Okur, S., Zhang, Z., Sarheed, M., Nick, P., Lemmer, U., & Heinke, L. (2020) · Sensors and Actuators B: Chemical · doi:10.1016/j.snb.2019.127502 · Cited by 74
Metadata
- Authors
- Achmann, S., Hagen, G., Kita, J., Malkowsky, I. M., Kiener, C., & Moos, R.
- Venue
- Sensors
- Publisher
- MDPI AG
- Published
- 2009-03-06
- Volume
- 9
- Issue
- 3
- Pages
- 1574-1589
- ISSN
- 1424-8220 (ISSN-L)
- OpenAlex
- W2043206028
- Cited by
- 423
- References
- 1
- FWCI
- 17.95
- Type
- journal article
- Language
- en
- Open access
- gold
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- Achmann, S., Hagen, G., Kita, J., Malkowsky, I. M., Kiener, C., & Moos, R. (2009). Metal-Organic Frameworks for Sensing Applications in the Gas Phase. Sensors. https://doi.org/10.3390/s90301574
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