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Metal-Organic Frameworks for Sensing Applications in the Gas Phase

Open access
Achmann, Sabine, Hagen, Gunter, Kita, Jaroslaw, Malkowsky, Itamar M., Kiener, Christoph, Moos, Ralf·2009·Sensors

Abstract

Several metal-organic framework (MOF) materials were under investigated to test their applicability as sensor materials for impedimetric gas sensors. The materials were tested in a temperature range of 120 °C - 240 °C with varying concentrations of O2, CO2, C3H8, NO, H2, ethanol and methanol in the gas atmosphere and under different test gas humidity conditions. Different sensor configurations were studied in a frequency range of 1 Hz -1 MHz and time-continuous measurements were performed at 1 Hz. The materials did not show any impedance response to O2, CO2, C3H8, NO, or H2 in the gas atmospheres, although for some materials a significant impedance decrease was induced by a change of the ethanol or methanol concentration in the gas phase. Moreover, pronounced promising and reversible changes in the electric properties of a special MOF material were monitored under varying humidity, with a linear response curve at 120 °C. Further investigations were carried out with differently doped MOF materials of this class, to evaluate the influence of special dopants on the sensor effect.

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Metadata

Authors
Achmann, S., Hagen, G., Kita, J., Malkowsky, I. M., Kiener, C., & Moos, R.
Venue
Sensors
Publisher
MDPI AG
Published
2009-03-06
Volume
9
Issue
3
Pages
1574-1589
ISSN
1424-8220 (ISSN-L)
OpenAlex
W2043206028
Cited by
423
References
1
FWCI
17.95
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Metal-Organic Frameworks for Sensing Applications in the Gas Phase. https://app.cochat.ai/papers/10.3390/s90301574
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Achmann, S., Hagen, G., Kita, J., Malkowsky, I. M., Kiener, C., & Moos, R. (2009). Metal-Organic Frameworks for Sensing Applications in the Gas Phase. Sensors. https://doi.org/10.3390/s90301574

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