Stable and metastable solubility diagrams for the system CaCO3 — MgCO3 — H2O at ordinary temperature
Open accessAbstract
La solubilité dans l'eau d'un système binaire de carbonates est régie par le produit total de solubilité, qui est la somme ∑∏ des produits partiels de solubilité des deux pôles. ∑∏, tracé en fonction du titre molaire de la phase solide et de celui dans la solution aqueuse, donne des courbes semblables aux diagrammes de phase pour la tension de vapeur de mélanges liquides. Le diagramme stable CaCO₃ — MgCO₃ — H₂O comprend deux points eutectiques stables à cause de l'intervention de la dolomite comme phase intermédiaire. La solubilité des calcites magnésiennes est caractérisée par des états métastables qui se produisent par suite de transgressions de plusieurs limites de miscibilité solide.
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The intrinsic difficulty to precipitate both proto- and ordered-dolomite is attributed to the Mg-hydration effect.
“the intrinsic difficulty to precipitate both proto- and ordered-dolomite is attributed to the Mg-hydration effect”
From Experimental evidence for abiotic formation of low-temperature proto-dolomite facilitated by clay minerals (2019) · cites this paper as Lippmann, 1982
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Dolomite: occurrence, evolution and economically important associations
Warren, J. (2000) · Earth-Science Reviews · doi:10.1016/s0012-8252(00)00022-2 · Cited by 1,435 · see citing works
Prieto, M., Fernández-González, A., Putnis, A., & Fernández-Díaz, L. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00160-9 · Cited by 156 · see citing works
Liu, D., Xu, Y., Papineau, D., Yu, N., Fan, Q., Qiu, X., & Wang, H. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.12.036 · Cited by 141 · see citing works
Mucci, A. (2004) · Aquatic Geochemistry · doi:10.1023/b:aqua.0000038958.56221.b4 · Cited by 94 · see citing works
Glynn, P. D. (1991) · Computers & Geosciences · doi:10.1016/0098-3004(91)90090-z · Cited by 74 · see citing works
Thermodynamic and Kinetic Studies of Dolomite Formation: A Review
Chen, C., Zhong, H., Wang, X., Ning, M., Wang, X., Ge, Y., Wang, H., Tang, R., & Hou, M. (2023) · Minerals · doi:10.3390/min13121479 · Cited by 43 · see citing works
Liu, D., Xu, Y., Yu, Q., Yu, N., Qiu, X., Wang, H., & Papineau, D. (2020) · Journal of Asian Earth Sciences · doi:10.1016/j.jseaes.2020.104301 · Cited by 32 · see citing works
- Authors
- Lippmann, F.
- Corresponding author
- Lippmann, Friedrich
- Venue
- Bulletin de Minéralogie
- Publisher
- PERSEE Program
- Published
- 1982
- Volume
- 105
- Issue
- 3
- Pages
- 273-279
- ISSN
- 0180-9210 (ISSN-L)
- OpenAlex
- W2996350887
- Cited by
- 62
- References
- 0
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 5 · 2023: 4 · 2022: 3 · 2021: 1 · 2020: 2 · 2019: 5 · 2018: 1 · 2017: 1 · 2016: 3 · 2015: 1 · 2013: 1 · 2012: 1
- FWCI
- 1.04
- Type
- journal article
- Language
- fr
- Open access
- green
- www.persee.fr
- Licence
- cc-by-nc-sa
- Locations
- Bulletin de Minéralogie (publishedVersion)
- Périodiques Scientifiques en Édition Électronique (submittedVersion, cc-by-nc-sa)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Keywords
- solubility diagram, eutectic point, dolomite, metastable states, calcite, magnesium carbonate, phase equilibria
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