Elastic anomalies associated with the antiferroelectric phase transitions of PbHfO3 single crystals
Open accessAbstract
The temperature dependence of the elastic properties of antiferroelectric PbHfO 3 was investigated by using Brillouin scattering. The two structural phase transitions of antiferroelectricantiferroelectric-paraelectric phases were clearly identified from the discontinuous changes in the acoustic mode frequencies and the hypersonic damping. The substantial softening of the mode frequency, along with the remarkable increase in the acoustic damping observed in the paraelectric phase, indicated the formation of precursor noncentrosymmetric (polar) clusters and their coupling to the acoustic waves. This was corroborated by the observation of quasi-elastic central peaks, the intensity of which grew upon cooling toward the Curie point. The obtained relaxation time exhibited a slowing-down behavior, suggesting that the dynamics of the precursor clusters became more sluggish on approaching the phase transition temperature.
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The maximum permittivity falls between the temperatures of the two transitions observed in bulk PHO around 160 °C and 210 °C.
“The maximum of permittivity falls in between the temperatures of the two transitions observed in bulk PHO around 160 ○ C and 210 ○ C. 35,36”
From The other model antiferroelectric: PbHfO3 thin films from ALD precursors (2021) · cites this paper as [36]
The Introduction (p. 3) places PbHfO3’s two phase transitions at approximately 160 °C and 210 °C. The paper examines elastic properties, however, and the passages on the transitions (Results and Discussion, p. 5) do not establish that the permittivity reaches its maximum between them; searches for a permittivity or dielectric maximum found no such passage. (LLM, conf=0.86)
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- Authors
- Ko, J.-H., Roleder, K., Majchrowski, A., & Bussmann-Holder, A.
- Affiliations
- Hallym University (KR)
- University of Silesia in Katowice (PL)
- Military University of Technology in Warsaw (PL)
- Corresponding author
- Ko, Jae-Hyeon
- Venue
- Journal of the Korean Physical Society
- Publisher
- Korean Physical Society
- Published
- 2014-04
- Volume
- 64
- Issue
- 8
- Pages
- 1169-1173
- ISSN
- 0374-4884 (ISSN-L)
- 1976-8524
- OpenAlex
- W2095046878
- Cited by
- 20
- References
- 26
- Citations by year
- 2026: 2 · 2025: 3 · 2022: 2 · 2021: 1 · 2020: 2 · 2018: 1 · 2017: 1 · 2016: 1 · 2015: 5 · 2014: 2
- FWCI
- 1.36
- Type
- journal article
- Language
- en
- Open access
- green
- arxiv.org
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Journal of the Korean Physical Society (publishedVersion)
- arXiv (Cornell University) (submittedVersion)
- arXiv (Cornell University)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
- Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Keywords
- PbHfO3, antiferroelectric phase transition, elastic anomalies, acoustic mode softening, quasielastic scattering, relaxation time, Brillouin scattering, single crystals, Curie temperature
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