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Determination of ultra‐low oxygen concentrations in oxygen minimum zones by the STOX sensor

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Revsbech, Niels Peter, Larsen, Lars Hauer, Gundersen, Jens, Dalsgaard, Tage, Ulloa, Osvaldo, Thamdrup, Bo·2009·Limnology and Oceanography: Methods

Abstract

The methods used until now have not been able to reliably resolve O 2 concentrations in oceanic oxygen minimum zones below 1–2 µmol L−1. We present a new amperometric sensor for the determination of ultra‐low O 2 concentrations under in situ conditions. The electrochemical STOX O 2 sensor contains a primary sensing cathode and a secondary cathode that, when polarized, prevents entry of O 2 into the sensor. This arrangement enables frequent in situ zero calibration and confers the sensor with a detection limit of 1‐10 nmol L−1 O 2, even during application on a Conductivity‐Temperature‐Depth (CTD) profiler at great water depths. The sensor was used during the Galathea 3 Expedition to demonstrate that the core of the oxygen minimum zone (OMZ) off Peru contained < 2 nM O 2. Application in a reactor on board demonstrated that changes in O 2 concentrations in OMZ water containing < 200 nmol L−1 O 2 could be monitored over periods of hours to days. The linear decrease in O 2 concentration in the reactor indicated very low (< 20 nmol L−1) half saturation constants for the O 2 respiring microbial community.

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Metadata

Authors
Revsbech, N. P., Larsen, L. H., Gundersen, J., Dalsgaard, T., Ulloa, O., & Thamdrup, B.
Venue
Limnology and Oceanography: Methods
Publisher
Wiley
Published
2009-05
Volume
7
Issue
5
Pages
371-381
ISSN
1541-5856 (ISSN-L)
OpenAlex
W1523470136
Cited by
268
References
0
FWCI
9.42
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Determination of ultra‐low oxygen concentrations in oxygen minimum zones by the STOX sensor. https://app.cochat.ai/papers/10.4319/lom.2009.7.371
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Revsbech, N. P., Larsen, L. H., Gundersen, J., Dalsgaard, T., Ulloa, O., & Thamdrup, B. (2009). Determination of ultra‐low oxygen concentrations in oxygen minimum zones by the STOX sensor. Limnology and Oceanography: Methods. https://doi.org/10.4319/lom.2009.7.371

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