The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics
Open accessAbstract
Abstract. We develop the thermodynamic underpinnings of a two-dimensional volatility basis set (2D-VBS) employing saturation mass concentration (Co) and the oxygen content (O:C) to describe volatility, mixing thermodynamics, and chemical evolution of organic aerosol. The work addresses a simple question: "Can we reasonably constrain organic-aerosol composition in the atmosphere based on only two measurable organic properties, volatility and the extent of oxygenation?" This is an extension of our earlier one-dimensional approach employing volatility only (C* = γ Co, where γ is an activity coefficient). Using available constraints on bulk organic-aerosol composition, we argue that one can reasonably predict the composition of organics (carbon, oxygen and hydrogen numbers) given a location in the Co – O:C space. Further, we argue that we can constrain the activity coefficients at various locations in this space based on the O:C of the organic aerosol.
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Cites
Evolution of Organic Aerosols in the Atmosphere
Jimenez, J. L., Canagaratna, M. R., Donahue, N. M., Prevot, A. S. H., Zhang, Q., Kroll, J. H., DeCarlo, P. F., Allan, J. D., Coe, H., Ng, N. L., et al. (2009) · Science · doi:10.1126/science.1180353 · Cited by 4,167
Self-citationMolecular Thermodynamics of Fluid-Phase Equilibria
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Self-citationAiken, A. C., DeCarlo, P. F., Kroll, J. H., Worsnop, D. R., Huffman, J. A., Docherty, K. S., Ulbrich, I. M., Mohr, C., Kimmel, J. R., Sueper, D., et al. (2008) · Environmental Science & Technology · doi:10.1021/es703009q · Cited by 1,492
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Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol
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Cited by
Formation of Urban Fine Particulate Matter
Zhang, R., Wang, G., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang, W., Hu, M., & Wang, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00067 · Cited by 1,426
Bianchi, F., Kurtén, T., Riva, M., Mohr, C., Rissanen, M. P., Roldin, P., Berndt, T., Crounse, J. D., Wennberg, P. O., Mentel, T. F., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00395 · Cited by 1,084
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Self-citationKoop, T., Bookhold, J., Shiraiwa, M., & Pöschl, U. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22617g · Cited by 785
Pöschl, U., & Shiraiwa, M. (2015) · Chemical Reviews · doi:10.1021/cr500487s · Cited by 657
Metadata
- Authors
- Donahue, N. M., Epstein, S. A., Pandis, S. N., & Robinson, A. L.
- Venue
- Atmospheric Chemistry and Physics
- Publisher
- Copernicus GmbH
- Published
- 2011-04-07
- Volume
- 11
- Issue
- 7
- Pages
- 3303-3318
- ISSN
- 1680-7316 (ISSN-L)
- 1680-7324
- OpenAlex
- W2127281457
- Cited by
- 890
- References
- 45
- FWCI
- 18.10
- Type
- journal article
- Language
- en
- Open access
- gold
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