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Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes
Open accessAbstract
Rechargeable Li-air battery is a candidate for post Li-ion battery with high energy density. In this paper, the rechargeability of Li-air battery over 100 cycles was confirmed and its capacity retention over 60% was achieved. Nevertheless, a large voltage gap between the discharge-charge profiles was observed. Here, a discharged product formed on a cathode was investigated by TEM observation and FT-IR spectroscopy. It was found that the main product formed in discharge was not an ideal compound, Li2O2, but was carbonate species issued from the decomposition of carbonate-based electrolyte solvent.
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Cited by
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Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Batteries and fuel cells for emerging electric vehicle markets
Cano, Z. P., Banham, D., Ye, S., Hintennach, A., Lu, J., Fowler, M., & Chen, Z. (2018) · Nature Energy · doi:10.1038/s41560-018-0108-1 · Cited by 2,873
Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries
Lu, Y.-C., Gasteiger, H. A., & Shao-Horn, Y. (2011) · Journal of the American Chemical Society · doi:10.1021/ja208608s · Cited by 567
From lithium to sodium: Cell chemistry of room temperature sodium–air and sodium–sulfur batteries
Adelhelm, P., Hartmann, P., Bender, C. L., Busche, M., Eufinger, C., & Janek, J. (2015) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.6.105 · Cited by 478
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Metadata
- Authors
- MIZUNO, F., NAKANISHI, S., KOTANI, Y., YOKOISHI, S., & IBA, H.
- Venue
- Electrochemistry
- Publisher
- The Electrochemical Society of Japan
- Published
- 2010
- Volume
- 78
- Issue
- 5
- Pages
- 403-405
- ISSN
- 1344-3542 (ISSN-L)
- 2186-2451
- OpenAlex
- W2092742983
- Cited by
- 403
- References
- 0
- FWCI
- 37.63
- Type
- journal article
- Language
- en
- Open access
- bronze
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- MIZUNO, F., NAKANISHI, S., KOTANI, Y., YOKOISHI, S., & IBA, H. (2010). Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes. Electrochemistry. https://doi.org/10.5796/electrochemistry.78.403
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