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Cited by 204Solid-state spectroscopy and crystallographyCrystal Structures and PropertiesMineralogy and Gemology Studies

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Infrared studies of aragonite, calcite, and vaterite type structures in the borates, carbonates, and nitrates

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Weir, C. E., Lippincott, Ellis R.·1961·Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
DOI 10.6028/jres.065a.021PMC PMC5287277
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Abstract

Infrared absorption spectra have been obtained on the alkali nitrates, the divalent metal carbonates, and the rare earth borates which assume the aragonite, calcite, or vaterite crystal structures. It was observed that similar structures give rise to analogous spectra except for the carbonate and borates having the vaterite structure. The marked differences observed in these latter spectra are discussed. Frequency shifts produced by cation substitution are ascribed to repulsion between closed electron shells of oxygen atoms. It is concluded that this repulsive force determines the structure type in the rare earth borates.

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Crossref · 10.6028/jres.065a.021

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1 of 1 references verified0 citation errors · 0 not checkable

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Figures

Figure 1 Infrared absorption spectrum of LuBO3 (calcite structure).
Figure 1 Infrared absorption spectrum of LuBO3 (calcite structure).CC0 · PubMed Central
Figure 2 Infrared absorption spectrum of CdCO3 (calcite structure).
Figure 2 Infrared absorption spectrum of CdCO3 (calcite structure).CC0 · PubMed Central
Figure 3 Infrared absorption spectrum of LuBO2 (calcite structure).
Figure 3 Infrared absorption spectrum of LuBO2 (calcite structure).CC0 · PubMed Central
Figure 4 Infrared absorption spectrum of KNO3 (aragonite structure).
Figure 4 Infrared absorption spectrum of KNO3 (aragonite structure).CC0 · PubMed Central
Figure 5 Infrared absorption spectrum of PbCO3 (aragonite structure).
Figure 5 Infrared absorption spectrum of PbCO3 (aragonite structure).CC0 · PubMed Central
Figure 6 Infrared absorption spectrum of NdBO3 (aragonite structure).
Figure 6 Infrared absorption spectrum of NdBO3 (aragonite structure).CC0 · PubMed Central
Figure 7 Infrared absorption spectrum of CaCO3 (vaterite structure).
Figure 7 Infrared absorption spectrum of CaCO3 (vaterite structure).CC0 · PubMed Central
Figure 8 Infrared absorption spectrum of SmBO3 (vaterite structure).
Figure 8 Infrared absorption spectrum of SmBO3 (vaterite structure).CC0 · PubMed Central
Figure 9 Infrared absorption spectrum of YBO3 (vaterite structure).
Figure 9 Infrared absorption spectrum of YBO3 (vaterite structure).CC0 · PubMed Central
Figure 10 Infrared absorption spectrum of LuBO3 (vaterite structure).
Figure 10 Infrared absorption spectrum of LuBO3 (vaterite structure).CC0 · PubMed Central
Figure 11 Infrared absorption spectrum of CsNO3.
Figure 11 Infrared absorption spectrum of CsNO3.CC0 · PubMed Central
Figure 12 Infrared absorption spectrum of LaBO3 (high temperature structure).
Figure 12 Infrared absorption spectrum of LaBO3 (high temperature structure).CC0 · PubMed Central
Figure 13 Infrared absorption spectrum of NdBO3 (high temperature structure).
Figure 13 Infrared absorption spectrum of NdBO3 (high temperature structure).CC0 · PubMed Central
Figure 14 Effect of ionic radius of cation on position of 930 cm−l band in borate type vaterites.
Figure 14 Effect of ionic radius of cation on position of 930 cm−l band in borate type vaterites.CC0 · PubMed Central
Figure 15 Effect of ionic radius of cation on position of 710 cm−1 band in borate type vaterites.
Figure 15 Effect of ionic radius of cation on position of 710 cm−1 band in borate type vaterites.CC0 · PubMed Central
Figure 16 Effect of ionic radius of cation on position of 570 cm−1 band in borate type vaterites.
Figure 16 Effect of ionic radius of cation on position of 570 cm−1 band in borate type vaterites.CC0 · PubMed Central

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Citations

Cites

Show all 1 references

Research works printed but not linked: 14

  1. [2]2. R. M. H exter , Spectrochim . Acta 10, 281 (1958) .
  2. [3]3. G. Baron, S. Cailliere, R. Lagrange, a nd T. Pobeguin, Bull . Soc. Fra n. Min. Cryst. 82, 150 (1959).
  3. [5]5. J . L . W ray a nd F. Daniels, J. Amer. Chem. Soc. 79, 2031 (1957).
  4. [7]7. D. F. I-Io l'ni g, J. Chem. Phys. 16,1063 (1948).
  5. [8]8. R. S. I-Ia. lford , J. Chem. Phys. 14, 8 (1946) .
  6. [10]10. H ans-Jurge n Meyer, Angew. Chem. 71, 678 (1959).
  7. [11]11. L . H. Ah rens, Geochim Cosmochim Acta 2, 155 (1952).
  8. [14]14. S. Bhagavantam a nd T. Venkataray ud o, Proc. Indian Acad. Sci. A9, 224 (1939); A13, 543 (1941).
  9. [15]15. C. K. I-luang and P. F. K err, Am. Mineral. 45, 311 (1960) .
  10. [16]16. W. C. Steele and J. C. D eciu s, J. Chem. Phys. 25, 1184 (1955) .
  11. [17]17. J. C. Decius, J. Chem. Phys. 23,1290 (1955).
  12. [18]18. L . Pau lin g, The nature of the chemical bond, ch . X . (Cornell Univ. Press, Ithaca, N. Y., 1948).
  13. [20]20. J . R. Clark, Acta Cryst. 12, 69 (1958).
  14. [21]21. C. L. Christ, Am. Mineral. 45, 334 (1960) .

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Metadata

Authors
Weir, C. E., & Lippincott, E. R.
Venue
Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
Publisher
National Institute of Standards and Technology (NIST)
Published
1961-05
Volume
65A
Issue
3
Pages
173
ISSN
0022-4332 (ISSN-L)
DOI
10.6028/jres.065a.021
PMC
PMC5287277
OpenAlex
W2328054148
Semantic Scholar
8a9a1e3f1674775299acab01da41c4a43e37ccfe
Cited by
202
References
1
Citations by year
2026: 6 · 2025: 13 · 2024: 11 · 2023: 10 · 2022: 7 · 2021: 10 · 2020: 9 · 2019: 14 · 2018: 6 · 2017: 7 · 2016: 6 · 2015: 11 · 2013: 1
FWCI
1.42
Type
journal article
Language
en
Open access
Licence
public-domain
Locations
  • Journal of Research of the National Bureau of Standards Section A Physics and Chemistry (publishedVersion, public-domain)
  • Europe PMC (PubMed Central) (publishedVersion, public-domain)
  • PubMed Central (publishedVersion, public-domain)
  • PubMed (publishedVersion)
  • National Institute of Standards and Technology (NIST) (submittedVersion, public-domain)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Crystal Structures and Properties
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
Keywords
calcite structure, rare earth borates, alkali metal nitrates, crystal structure determination, infrared spectra, cation substitution, frequency shift

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