Procedures for homogeneous anionic polymerization
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This report is a review of the procedures and equipment used in the preparation of polymers of predictable molecular weights and narrow molecular weight distributions. The monomers considered in detail are styrene, α-methylstyrene, isoprene, and butadiene.
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In hydrocarbon solvents, anionic polymerization proceeds very slowly, so the sequence in which reagents are added to the solvent is not necessarily critical.
“The kinetics of polymerization in hydrocarbon media are very slow, and this means that the order of incorporation of reagents into the solvent is not necessarily crucial.”
From Experimental techniques in high-vacuum anionic polymerization (2005) · cites this paper as [1]
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Anionic polymerization of isoprene at low concentrations of polyisoprenyllithium
Fetters, L. J. (1965) · Journal of Research of the National Bureau of Standards Section A Physics and Chemistry · doi:10.6028/jres.069a.018 · Cited by 16 · see citing works
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Research works printed but not linked: 49
- M. Szwarc, Nature 178, 1168 (1956).
- M. Szwarc, M. Levy, and R. Milkovich , J . Am. Chern. Soc. 78, 2656 (1956).
- P. J. Flory, J. Am . Chern . Soc. 62, 1561 (1940).
- R. Waac k, A. Rembaum, J. D. Coo mbes, and M. Szwarc, J. Am. Chern. Soc. 79,2026 (1957).
- H. McCormick, J. Po lymer Sci. 36,341 (1959).
- F. Wenger, Makromoleculare Chern. 36, 200 (1960); 64, 151 (1963).
- T . Lyssy, Helv. C him. Acta. 42,2245 (1959).
- H.•J. Cantow, Makromoleculare Chern. 30, 169 (1959).
- G. Meyerhoff, Z. physik Chern. (Frankfurt) 23, 100 (1960).
- J. M. G. Cowie, D. J. Worsfold, and S. Bywater, Trans. Fara• day Soc. 57,705 (1961). In iti ator Solvent Seq uence Ref. Na-naphthalene THF' ByAxBy 2,87 AxByAx .
- S.•P. S. Yen , Makromo lec ulare Chern. 81,152 (1965).
- H. McCormick, J. Polymer Sci. 41,327 (1959);
- F. Wenger J. Am. Chern. Soc. 82, 4281 (1960); Makromolec ulare Chern. 37,143(1960).
- A. F. Sirianni , D. J. Worsfold , and S. Bywater, Trans. Faraday Soc. 55,2124 (1959).
- W. H. Beattie and C. Booth , J. AppL Polymer Sci. 7,507 (1963).
- S. E. Bresler, A. A. Koro lkov, M. 1. Mosevitsky, and 1. Ya. Poddubnyi, ZhuL Tech. Fiz. 28, 114 (1958).
- J. F. Meier, Ph.D. Dissertation, University of Akron, 1963.
- W. T . Grubb and R. C. Osthoff, J. Am. Chern. Soc. 77,1405 (1955).
- C. Geacintov, J. Smid, and M. Szwarc, J . Am. Chern. Soc. 84, 2508 (1962).
- M. Szwarc and M. Litt, J. Phys. Chern. 62,568 (1958).
- D. J. Worsfo ld and S. Bywater, Can. J . Chem. 38,1891 (1960).
- B. D. Co leman, F. Gornick , and G. Weiss, J. Chern. Phys. 39,3233 (1963).
- B. J. Mair, D. J. Termini, C. B. Willin gham, and F. D. Rossini , J. Res. NBS 37, 229 (1946) RP1744.
- N. D.Scott and J. F. Walker, Ind. Eng. Chern . 32,312 (1940).
- R. K. Graham, D. L. Dunkelburger and W. E. Good e, J. Am. Chem. Soc. 82,400 (1960).
- H. Gilman and F. K. Ca rtl edge. J. Organome lalli c C he m. 2, 447 (1964).
- T. V. Talalaeva and K. A. Kocheskov , Zhur. Obs hc he i Khim . 23,392 (1953): J. Gen. C hem. U.S.S.R. (Engl. Iran s.) 23 , 399 (1953).
- H. Gi lman and R. D. Gorsich , J. Org. Che m. 23, 550 (1958):
- C. C. Easl , P. F. Lyn ch , and D. Margeri so n . Po lymer 4,139 (1963).
- J H. Hsie h, J. P olyme r Sci . 3A, 153, 173 (1965).
- H. Sinn. C. Lundborg. and O. T. On sa ge r. Makrumol ec ulare C he m. 70,222 (1964).
- 60J M. A. Weinel', C. Vuge l, a nd R. Wes t. lnurgan ic C he m. 1, 654 (1962).
- L. J . Fell e rs, J. Polymer Sci. 28, 425 (1964).
- F. A. Bovey and G. V. D. Ti e rs, Advances in Polymer Sc i. 3, 139 (1963).
- 67J D. Braun, W. Be tz, and W. Ke rn. Makromol ec ulare C he m. 42, 89 (1960).
- D. J. Worsfuld and S. Bywal e r. Makromolekulare C he rn. 65, 245 (1963).
- 70J D. M. Wil es and S. Bywaler, J. Phys. Chem. 68, 1983 (1964) .
- T. L. Brown. J. A. Ladd, and G. N. Ne wman , .I . Orga nom elalli c Chern. 3, 1 (1965).
- I. Kunlz and A. Gerbe r, J. Pulym e r Sci. 42,299 (1960). 433
- 79J M. Morloll . T. E. H e lminiak, S . D. Cadkary, and F. Buec he, .1 . Po lymcr Sci. 57,471 (1962).
- 80J T. A. Orofino a nd F. Wenger, J. Phys. Chern. 67,566 (1963).
- A. A. Kurulkuv. I.. A. Shibayov. L. M. Pyrakuv. V. G. Aldo• shin, and S. Ya. Fenkel , Vysokomol. Soed. 1,443 (1959).
- R. K. Graham . D. L. Dunkelberger. and E. S. Co hn . .1. Poly. mer Sci. 42,501 (1960).
- K. Norc. H. Kaw aZlira . T. Moriya ma , and S. Y"s hika. Makr,,• mol e kulare Che rn . 83, 35 (1965).
- 96J H. Yu . A . .I. Hill'. alltl L. J. Fe ll e rs . .I. C he m. Ph ys . 44,2568 (1966): L. J. Fe u e rs a nd H. YlI , Polyme r Pre prinl s 7, 443 (1966).
- D. M Wil es and S. Bywal e r, Trans. Faraday Soc. 61,1 50 (1965).
- 109J A. V. Tobols ky and D. 13. Harll ey, J. Am. C hem. Soc. 84, 1391 (1962).
- 110J M. Szwarc and A. Remballm , J. Polymer Sci. 22,189 (1956).
- II:-;J C. G. Ove rb e rge r. E. M. Pearce, and N. Mayes , J. Po lyme r Sci. 34, 109 (1959).
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Experimental techniques in high-vacuum anionic polymerization
Uhrig, D., & Mays, J. W. (2005) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.21016 · Cited by 293 · see citing works
- Authors
- Fetters, L. J.
- Affiliations
- National Institute of Standards and Technology (US)
- Corresponding author
- Fetters, Lewis J.
- Venue
- Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
- Published
- 1966-09
- Volume
- 70A
- Issue
- 5
- Pages
- 421
- ISSN
- 0022-4332 (ISSN-L)
- PMC
- PMC6624691
- OpenAlex
- W2324406142
- Cited by
- 81
- References
- 1
- Citations by year
- 2023: 1 · 2018: 1 · 2016: 1 · 2015: 1
- FWCI
- 4.69
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of Research of the National Bureau of Standards Section A Physics and Chemistry (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- National Institute of Standards and Technology (NIST) (submittedVersion, public-domain)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- controlled radical polymerization, narrow molecular weight distribution, styrene, α-methylstyrene, isoprene, 1,3-butadiene, polymerization equipment
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