The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Circular Dichroism and Linear Dichroism
Abstract
Circular dichroism (CD) is the difference in absorption, A, of left and right circularly polarized light, Equation (1): For randomly oriented systems such as solutions of molecules, only chiral molecules will show any CD intensity corresponding to their absorption bands. Chiral molecules are those molecules that cannot be superposed on their mirror images. Chiral is derived from the Greek word χϵιρ meaning hand, hence the alternate term for chirality, ‘handedness’. Two molecules that are mirror images of each other are often referred to as enantiomers, and equimolar mixtures of two enatiomers form a racemic mixture, which has no net CD intensity in solution. CD can be used to analyze chiral structures such as protein secondary structure in molecules and to probe interactions between chiral molecules and other molecules. Linear dichroism (LD) is the difference in absorption of light linearly polarized parallel and perpendicular to an orientation axis, Equation (2): LD can be used to provide orientation information about subunits of a molecular system such as small molecules absorbed onto stretched films, flow‐oriented DNAs and fibrous proteins, and lipid bilayer systems.
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Cites
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Whitmore, L., & Wallace, B. A. (2004) · Nucleic Acids Research · doi:10.1093/nar/gkh371 · Cited by 2,338
Molecular Light Scattering and Optical Activity
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Atomic model of the actin filament
Holmes, K. C., Popp, D., Gebhard, W., & Kabsch, W. (1990) · Nature · doi:10.1038/347044a0 · Cited by 1,697
Circular Dichroism and Linear Dichroism
Rodger, A., & Norden, B. (1997) · doi:10.1093/oso/9780198558972.001.0001 · Cited by 797
Self-citation(1995) · Choice Reviews Online · doi:10.5860/choice.32-6212 · Cited by 755
Quantenmechanische Theorie der nat�rlichen optischen Aktivit�t von Fl�ssigkeiten und Gasen
Rosenfeld, L. (1929) · Zeitschrift f�r Physik · doi:10.1007/bf01342393 · Cited by 642
Analyzing protein circular dichroism spectra for accurate secondary structures
Johnson, W. C. (1999) · Proteins: Structure, Function, and Genetics · doi:10.1002/(sici)1097-0134(19990515)35:3<307::aid-prot4>3.0.co;2-3 · Cited by 638
Secondary Structure of Proteins Through Circular Dichroism Spectroscopy
Johnson, W. C. (1988) · Annual Review of Biophysics and Biophysical Chemistry · doi:10.1146/annurev.bb.17.060188.001045 · Cited by 552
Cited by
How to study proteins by circular dichroism
Kelly, S. M., Jess, T. J., & Price, N. C. (2005) · Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics · doi:10.1016/j.bbapap.2005.06.005 · Cited by 3,351
The Copigmentation of Anthocyanins and Its Role in the Color of Red Wine: A Critical Review
Boulton, R. (2001) · American Journal of Enology and Viticulture · doi:10.5344/ajev.2001.52.2.67 · Cited by 1,206
Chirality detection of enantiomers using twisted optical metamaterials
Zhao, Y., Askarpour, A. N., Sun, L., Shi, J., Li, X., & Alù, A. (2017) · Nature Communications · doi:10.1038/ncomms14180 · Cited by 622
Sticky-End Assembly of a Designed Peptide Fiber Provides Insight into Protein Fibrillogenesis
Pandya, M. J., Spooner, G. M., Sunde, M., Thorpe, J. R., Rodger, A., & Woolfson, D. N. (2000) · Biochemistry · doi:10.1021/bi000246g · Cited by 344
Self-citationHarris, W. R., & Messori, L. (2002) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(02)00037-1 · Cited by 145
Metadata
- Authors
- Rodger, A.
- Venue
- Encyclopedia of Analytical Chemistry
- Publisher
- Wiley
- Published
- 2014-01-13
- Pages
- 1-34
- OpenAlex
- W2172047227
- Cited by
- 469
- References
- 22
- Type
- reference entry
- Language
- en
- Open access
- closed
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