Comparison of shape memory metals and polymers
Abstract
Both, metals and polymers can show the one‐way shape memory effect or rubber‐like elasticity. The origin of these effects in the two types of materials is discussed. It is shown that there is an analogy between the high temperature phases β: crystalline austenite in metals and random coils in polymers. There are differences in the low temperature phases α: a domain structure is typical for metallic martensite, and stretched chains for polymers. Prerequisite for memory and superelastic effects is a complete structural reversibility during a β – α transformation cycle.
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At the molecular level, staying above the shape fixing temperature would lead to relaxation of an applied strain if the polymer is unloaded at that temperature, due to structural recoil of switching segments as soon as stress is released according to normal rubber elasticity.
“At the molecular level, staying above the shape fixing temperature would lead to relaxation of an applied strain, if the polymer is unloaded at that temperature, due to structural recoil of the switching segments as soon as stress is released according to normal rubber elasticity [23].”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [23]
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- Authors
- Hornbogen, E.
- Affiliations
- Ruhr University Bochum (DE)
- Corresponding author
- Hornbogen, E.
- Venue
- Advanced Engineering Materials
- Publisher
- Wiley
- Published
- 2006-02
- Volume
- 8
- Issue
- 1-2
- Pages
- 101-106
- ISSN
- 1438-1656 (ISSN-L)
- 1527-2648
- OpenAlex
- W1970773278
- Cited by
- 99
- References
- 14
- Citations by year
- 2026: 2 · 2025: 6 · 2024: 2 · 2023: 5 · 2022: 5 · 2021: 6 · 2020: 12 · 2019: 9 · 2018: 4 · 2017: 6 · 2016: 3 · 2015: 4 · 2014: 4 · 2013: 6 · 2012: 2
- FWCI
- 2.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Engineering Materials (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Shape Memory Alloy Transformations
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- shape memory effect, shape memory polymers, shape memory alloys, one-way shape memory effect, rubber elasticity, superelasticity, martensitic transformation, random coil, structural reversibility, phase transformation
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