The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
High‐Nanofiller‐Content Graphene Oxide–Polymer Nanocomposites via Vacuum‐Assisted Self‐Assembly
Abstract
Highly ordered, homogeneous polymer nanocomposites of layered graphene oxide are prepared using a vacuum‐assisted self‐assembly (VASA) technique. In VASA, all components (nanofiller and polymer) are pre‐mixed prior to assembly under a flow, making it compatible with either hydrophilic poly(vinyl alcohol) (PVA) or hydrophobic poly(methyl methacrylate) (PMMA) for the preparation of composites with over 50 wt% filler. This process is complimentary to layer‐by‐layer assembly, where the assembling components are required to interact strongly (e.g., via Coulombic attraction). The nanosheets within the VASA‐assembled composites exhibit a high degree of order with tunable intersheet spacing, depending on the polymer content. Graphene oxide–PVA nanocomposites, prepared from water, exhibit greatly improved modulus values in comparison to films of either pure PVA or pure graphene oxide. Modulus values for graphene oxide–PMMA nanocomposites, prepared from dimethylformamide, are intermediate to those of the pure components. The differences in structure, modulus, and strength can be attributed to the gallery composition, specifically the hydrogen bonding ability of the intercalating species
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Cites
Graphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
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Cited by
Graphene-polymer nanocomposites for structural and functional applications
Hu, K., Kulkarni, D. D., Choi, I., & Tsukruk, V. V. (2014) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.03.001 · Cited by 1,085
Functional Composite Materials Based on Chemically Converted Graphene
Bai, H., Li, C., & Shi, G. (2011) · Advanced Materials · doi:10.1002/adma.201003753 · Cited by 1,080
Hung, W.-S., Tsou, C.-H., De Guzman, M., An, Q.-F., Liu, Y.-L., Zhang, Y.-M., Hu, C.-C., Lee, K.-R., & Lai, J.-Y. (2014) · Chemistry of Materials · doi:10.1021/cm5007873 · Cited by 787
On the Gelation of Graphene Oxide
Bai, H., Li, C., Wang, X., & Shi, G. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp1120299 · Cited by 668
Super-tough MXene-functionalized graphene sheets
Zhou, T., Wu, C., Wang, Y., Tomsia, A. P., Li, M., Saiz, E., Fang, S., Baughman, R. H., Jiang, L., & Cheng, Q. (2020) · Nature Communications · doi:10.1038/s41467-020-15991-6 · Cited by 578
Metadata
- Authors
- Putz, K. W., Compton, O. C., Palmeri, M. J., Nguyen, S. T., & Brinson, L. C.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2010-08-04
- Volume
- 20
- Issue
- 19
- Pages
- 3322-3329
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2141237492
- Cited by
- 560
- References
- 1
- FWCI
- 22.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Putz, K. W., Compton, O. C., Palmeri, M. J., Nguyen, S. T., & Brinson, L. C. (2010). High‐Nanofiller‐Content Graphene Oxide–Polymer Nanocomposites via Vacuum‐Assisted Self‐Assembly. Advanced Functional Materials. https://doi.org/10.1002/adfm.201000723
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