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Detonation Nanodiamond and Onion‐Like‐Carbon‐Embedded Polyaniline for Supercapacitors
Abstract
The detonation nanodiamond is a versatile low‐cost nanomaterial with tunable properties and surface chemistry. In this work, it is shown how the application of nanodiamond (ND) can greatly increase the performance of electrochemically active polymers, such as polyaniline (PANI). Symmetric supercapacitors containing PANI‐ND nanocomposite electrodes with 3–28 wt% ND show dramatically improved cycle stability and higher capacitance retention at fast sweep rate than pure PANI electrodes. Contrary to other PANI‐carbon nanocomposites, specific capacitance of the selected PANI electrodes with embedded ND increases after 10 000 galvanostatic cycles and reaches 640 F g−1, when measured in a symmetric two‐electrode configuration with 1 M H 2 SO 4 electrolyte. The demonstrated specific capacitance is 3–4 times higher than that of the activated carbons and more than 15 times higher than that of ND and onion‐like carbon (OLC).
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Cited by
Jiang, J., Li, Y., Liu, J., Huang, X., Yuan, C., & Lou, X. W. (. (2012) · Advanced Materials · doi:10.1002/adma.201202146 · Cited by 2,473
Conductive diamond: synthesis, properties, and electrochemical applications
Yang, N., Yu, S., Macpherson, J. V., Einaga, Y., Zhao, H., Zhao, G., Swain, G. M., & Jiang, X. (2019) · Chemical Society Reviews · doi:10.1039/c7cs00757d · Cited by 522
Review: carbon onions for electrochemical energy storage
Zeiger, M., Jäckel, N., Mochalin, V. N., & Presser, V. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta08295a · Cited by 474
Rational Design of Nanostructured Electrode Materials toward Multifunctional Supercapacitors
Yan, J., Li, S., Lan, B., Wu, Y., & Lee, P. S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201902564 · Cited by 426
Nanoforest of hierarchical Co3O4@NiCo2O4 nanowire arrays for high-performance supercapacitors
Zhang, G., Wang, T., Yu, X., Zhang, H., Duan, H., & Lu, B. (2013) · Nano Energy · doi:10.1016/j.nanoen.2013.07.008 · Cited by 294
Metadata
- Authors
- Kovalenko, I., Bucknall, D. G., & Yushin, G.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2010-08-30
- Volume
- 20
- Issue
- 22
- Pages
- 3979-3986
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1997747713
- Cited by
- 264
- References
- 0
- FWCI
- 9.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kovalenko, I., Bucknall, D. G., & Yushin, G. (2010). Detonation Nanodiamond and Onion‐Like‐Carbon‐Embedded Polyaniline for Supercapacitors. Advanced Functional Materials. https://doi.org/10.1002/adfm.201000906
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