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Evolution of Nanoporous Pt–Fe Alloy Nanowires by Dealloying and their Catalytic Property for Oxygen Reduction Reaction

Shui, Jiang‐lan, Chen, Chen, Li, James C. M.·2011·Advanced Functional Materials

Abstract

The short life and high cost of carbon‐supported Pt nanoparticle catalysts (Pt/C) are two main problems with proton exchange membrane fuel cells. Porous Pt alloy nanowires have more durability and catalytic activity than Pt/C. Dealloying is a facile way to make nanoporous Pt. However, the process of porosity formation is difficult to control. In this paper, electrospinning and chemical dealloying techniques are used to make long, thin and yet nanoporous Pt–Fe alloy nanowires. The evolution of nanoporosity is observed and studied. It is found that non‐uniform composition in the precursor PtFe 5 alloy nanowires helps the formation of nanoporous structure. The overall wire diameter is about 10–20 nm and the ligament diameter only 2–3 nm. These porous long nanowires interweave to form a self‐supporting network with a high specific activity, 2.3 times that of conventional Pt/C catalysts, and also have better durability.

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Metadata

Authors
Shui, J., Chen, C., & Li, J. C. M.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2011-07-11
Volume
21
Issue
17
Pages
3357-3362
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W1980381036
Cited by
229
References
4
FWCI
7.75
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Evolution of Nanoporous Pt–Fe Alloy Nanowires by Dealloying and their Catalytic Property for Oxygen Reduction Reaction. https://app.cochat.ai/papers/10.1002/adfm.201100723
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Shui, J., Chen, C., & Li, J. C. M. (2011). Evolution of Nanoporous Pt–Fe Alloy Nanowires by Dealloying and their Catalytic Property for Oxygen Reduction Reaction. Advanced Functional Materials. https://doi.org/10.1002/adfm.201100723

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