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High‐Throughput Fabrication of Uniform and Homogenous MOF Coatings
Abstract
We describe a novel method to produce monolithic, oriented, crystalline and highly porous coatings on solid substrates. By adopting the recently described liquid‐phase epitaxy (LPE) process developed to grow metal‐organic framework coatings (MOFs) on modified Au‐substrates to the spray method, we have prepared thick (μm) layers of several MOF types on modified Au‐substrates, including HKUST‐I and layer‐pillar MOFs. The spray method not only allows such SURMOFs to be grown much faster than with the LPE‐process but the dependence of layer thickness on the number of immersion cycles also provides valuable insights into the mechanism governing the layer‐by‐layer MOF formation process.
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Cited by
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Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Liu, J., & Wöll, C. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00315c · Cited by 698
Self-citationCurrent Status of Metal–Organic Framework Membranes for Gas Separations: Promises and Challenges
Shah, M., McCarthy, M. C., Sachdeva, S., Lee, A. K., & Jeong, H.-K. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie202038m · Cited by 494
Heinke, L., & Wöll, C. (2019) · Advanced Materials · doi:10.1002/adma.201806324 · Cited by 192
Self-citationNeufeld, M. J., Harding, J. L., & Reynolds, M. M. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b08773 · Cited by 116
Metadata
- Authors
- Arslan, H. K., Shekhah, O., Wohlgemuth, J., Franzreb, M., Fischer, R. A., & Wöll, C.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2011-09-09
- Volume
- 21
- Issue
- 22
- Pages
- 4228-4231
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2006850536
- Cited by
- 251
- References
- 0
- FWCI
- 5.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Arslan, H. K., Shekhah, O., Wohlgemuth, J., Franzreb, M., Fischer, R. A., & Wöll, C. (2011). High‐Throughput Fabrication of Uniform and Homogenous MOF Coatings. Advanced Functional Materials. https://doi.org/10.1002/adfm.201101592
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