Cited by 116Metal-Organic Frameworks: Synthesis and ApplicationsEnzyme Catalysis and ImmobilizationSurface Modification and Superhydrophobicity

Immobilization of Metal–Organic Framework Copper(II) Benzene-1,3,5-tricarboxylate (CuBTC) onto Cotton Fabric as a Nitric Oxide Release Catalyst

Neufeld, Megan J., Harding, Jacqueline L., Reynolds, Melissa M.·2015·ACS Applied Materials & Interfaces

Abstract

Immobilization of metal-organic frameworks (MOFs) onto flexible polymeric substrates as secondary supports expands the versatility of MOFs for surface coatings for the development of functional materials. In this work, we demonstrate the deposition of copper(II) benzene-1,3,5-tricarboxylate (CuBTC) crystals directly onto the surface of carboxyl-functionalized cotton capable of generating the therapeutic bioagent nitric oxide (NO) from endogenous sources. Characterization of the CuBTC-cotton material by XRD, ATR-IR, and UV-vis indicate that CuBTC is successfully immobilized on the cotton fabric. In addition, SEM imaging reveals excellent surface coverage with well-defined CuBTC crystals. Subsequently, the CuBTC-cotton material was evaluated as a supported heterogeneous catalyst for the generation of NO using S-nitrosocysteamine as the substrate. The resulting reactivity is consistent with the activity observed for unsupported CuBTC particles. Overall, this work demonstrates deposition of MOFs onto a flexible polymeric material with excellent coverage as well as catalytic NO release from S-nitrosocysteamine at therapeutic levels.

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Crossref · 10.1021/acsami.5b08773

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  • Reynolds and coworkers are developing MOF-NO generating catalysts with accessible catalytic sites and resistance to degradation, including Cu3(BTC)2, CuBTTri, and CuBTC.

    “Reynolds and coworkers are developing many MOF-NO generating catalysts with accessible catalytic sites and that have resistance to degradation, including Cu3(BTC)2 (BTC: 1,3,5-benzenetricarboxylate), Cu(II)1,3,5-benzene-tris-triazole (CuBTTri) and Cu(II)1,3,5-tricarboxylate (CuBTC).210–212”

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Authors
Neufeld, M. J., Harding, J. L., & Reynolds, M. M.
Affiliations
  • Colorado State University (US)
  • Colorado School of Mines (US)
Corresponding author
Reynolds, Melissa M.
Venue
ACS Applied Materials & Interfaces
Published
2015-11-23
Volume
7
Issue
48
Pages
26742-26750
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2428438873
Cited by
116
References
60
Citations by year
2026: 3 · 2025: 8 · 2024: 12 · 2023: 12 · 2022: 14 · 2021: 13 · 2020: 18 · 2019: 10 · 2018: 10 · 2017: 10 · 2016: 6
FWCI
3.56
Type
journal article
Language
en
Open access
closed
Locations
  • ACS Applied Materials & Interfaces (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • Division of Materials Research (DMR-1352201)
  • National Institute of Biomedical Imaging and Bioengineering (1R21EB016838-021)
  • Colorado State University
Topics
  • Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Enzyme Catalysis and Immobilization
  • Physical Sciences › Materials Science › Surfaces, Coatings and Films › Surface Modification and Superhydrophobicity
Keywords
HKUST-1, metal-organic frameworks, cotton fabric, nitric oxide release, heterogeneous catalysis, flexible polymeric substrates, surface coating
MeSH terms
Catalysis, Copper, Methylation, Nitric Oxide, Spectrum Analysis, Tricarboxylic Acids, X-Ray Diffraction, Cotton Fiber

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