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Highly Ordered Mesoporous Crystalline MoSe2 Material with Efficient Visible‐Light‐Driven Photocatalytic Activity and Enhanced Lithium Storage Performance
Abstract
Highly ordered mesoporous crystalline MoSe 2 is synthesized using mesoporous silica SBA‐15 as a hard template via a nanocasting strategy. Selenium powder and phosphomolybdic acid (H 3 PMo 12 O 40) are used as Se and Mo sources, respectively. The obtained products have a highly ordered hexagonal mesostructure and a rod‐like particle morphology, analogous to the mother template SBA‐15. The UV‐vis‐NIR spectrum of the material shows a strong light absorption throughout the entire visible wavelength region. The direct bandgap is estimated to be 1.37 eV. The high surface area MoSe 2 mesostructure shows remarkable photocatalytic activity for the degradation of rhodamine B, a model organic dye, in aqueous solution under visible light irradiation. In addition, the synthesized mesoporous MoSe 2 possess a reversible lithium storage capacity of 630 mAh g−1 for at least 35 cycles without any notable decrease. The rate performance of mesoporous MoSe 2 is much better than that of analogously synthesized mesoporous MoS 2, making it a promising anode for the lithium ion battery.
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Metadata
- Authors
- Shi, Y., Hua, C., Li, B., Fang, X., Yao, C., Zhang, Y., Hu, Y., Wang, Z., Chen, L., Zhao, D., & Stucky, G. D.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2012-10-30
- Volume
- 23
- Issue
- 14
- Pages
- 1832-1838
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2091919832
- Cited by
- 317
- References
- 2
- FWCI
- 7.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shi, Y., Hua, C., Li, B., Fang, X., Yao, C., Zhang, Y., Hu, Y., Wang, Z., Chen, L., Zhao, D., & Stucky, G. D. (2013). Highly Ordered Mesoporous Crystalline MoSe2 Material with Efficient Visible‐Light‐Driven Photocatalytic Activity and Enhanced Lithium Storage Performance. Advanced Functional Materials. https://doi.org/10.1002/adfm.201202144
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