A Novel MoSe2–Reduced Graphene Oxide/Polyimide Composite Film for Applications in Electrocatalysis and Photoelectrocatalysis Hydrogen Evolution
Abstract
Promising catalytic activity of MoSe2 in the hydrogen evolution reaction (HER) is synthesized on a new reduced graphene oxide/polyimide (rGO/PI) substrate by a simple electrochemical method. The MoSe2 nanoparticles have excellent photo‐responsive properties; the potential difference could reach 0.45 V with the photo‐responsive time just 0.6 s. Furthermore, MoSe2 thin film exhibits superior catalytic activity in the hydrogen evolution reaction (HER). It has a greater cathode current at more positive potential compared to other MoSe2 and MoS2, and the efficiency of H2 evolution is strongly influenced by illumination; this suggests that MoSe2 composite film has good photoelectrocatalysis properties for hydrogen evolution. Besides, both dark and illumination MoSe2 films exhibit extremely high stability in acidic solution as the HER catalytic activity shows no degradation after 100 cycles for two hours. All results indicate that MoSe2–rGO/PI composite film has potential to be a better catalyst for HER.
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Transition-metal dichalcogenides such as MoS2, MoSe2, CoS2, and WSe2 are promising HER catalysts due to their tunable band structure and intrinsic electrochemical activities.
“Transition-metal dichalcogenides (TMDs), such as MoS2, MoSe2 [9–12], CoS2 [13–16], WSe2 [17,18], have been recognized as promising HER catalysts due to their tunable band structure and intrinsic electrochemical activities.”
From Graphene/graphene nanoribbon aerogels as tunable three-dimensional framework for efficient hydrogen evolution reaction (2017) · cites this paper as [11]
MoSe2 is a promising noble-metal-free electrocatalyst for the hydrogen evolution reaction.
“Recent studies have proven that newly emerging two-dimensional molybdenum diselenide (MoSe2) is a promising noble-metal-free electrocatalyst for hydrogen evolution reaction (HER).”
From Cotton Wool Derived Carbon Fiber Aerogel Supported Few-Layered MoSe<sub>2</sub> Nanosheets As Efficient Electrocatalysts for Hydrogen Evolution (2016) · cites this paper as [32]
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Self-citation
- Authors
- Jia, L., Sun, X., Jiang, Y., Yu, S., & Wang, C.
- Affiliations
- Lanzhou University (CN)
- Corresponding author
- Wang, Chunming
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2014-09-05
- Volume
- 25
- Issue
- 12
- Pages
- 1814-1820
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2086512413
- Cited by
- 178
- References
- 42
- Citations by year
- 2025: 3 · 2024: 14 · 2023: 12 · 2022: 7 · 2021: 11 · 2020: 17 · 2019: 22 · 2018: 23 · 2017: 29 · 2016: 25 · 2015: 14
- FWCI
- 7.47
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Functional Materials (publishedVersion)
- Lanzhou University Institutional Repository (submittedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Keywords
- MoSe2, reduced graphene oxide, polyimide, composite films, hydrogen evolution reaction, photoelectrocatalysis, electrocatalysis, electrochemical synthesis, photoresponsivity, catalyst stability, acidic media
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