The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Self‐Supported Cobalt Phosphide Mesoporous Nanorod Arrays: A Flexible and Bifunctional Electrode for Highly Active Electrocatalytic Water Reduction and Oxidation
Abstract
Water splitting for the production of hydrogen and oxygen is an appealing solution to advance many sustainable and renewable energy conversion and storage systems, while the key fact depends on the innovative exploration regarding the design of efficient electrocatalysts. Reported herein is the growth of CoP mesoporous nanorod arrays on conductive Ni foam through an electrodeposition strategy. The resulting material of well‐defined mesoporosity and a high specific surface area (148 m 2 g−1) can be directly employed as a bifunctional and flexible working electrode for both hydrogen and oxygen evolution reactions, showing superior activities as compared with noble metal benchmarks and state‐of‐the‐art transition‐metal‐based catalysts. This is intimately related to the unique nanorod array electrode configuration, leading to excellent electric interconnection and improved mass transport. A further step is taken toward an alkaline electrolyzer that can achieve a current density of 10 mA cm−2 at a voltage around 1.62 V over a long‐term operation, better than the combination of Pt and IrO 2. This development is suggested to be readily extended to obtain other electrocatalysis systems for scale‐up water‐splitting technology.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
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Alternative energy technologies
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High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
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Cited by
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Non‐Noble Metal‐based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications
Wang, J., Xu, F., Jin, H., Chen, Y., & Wang, Y. (2017) · Advanced Materials · doi:10.1002/adma.201605838 · Cited by 1,769
Yan, Y., Xia, B. Y., Zhao, B., & Wang, X. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta08075h · Cited by 1,368
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Metadata
- Authors
- Zhu, Y., Liu, Y., Ren, T., & Yuan, Z.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2015-11-06
- Volume
- 25
- Issue
- 47
- Pages
- 7337-7347
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2145646973
- Cited by
- 765
- References
- 18
- FWCI
- 27.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhu, Y., Liu, Y., Ren, T., & Yuan, Z. (2015). Self‐Supported Cobalt Phosphide Mesoporous Nanorod Arrays: A Flexible and Bifunctional Electrode for Highly Active Electrocatalytic Water Reduction and Oxidation. Advanced Functional Materials. https://doi.org/10.1002/adfm.201503666
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