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Highly Oriented and Ordered Arrays from Block Copolymers via Solvent Evaporation
Abstract
A simple process of solvent evaporation is shown to produce highly ordered arrays of cylindrical microdomains in block copolymers with long‐range lateral order (see Figure). Solvent evaporation in thin films is unidirectional, producing a self‐assembly directed normal to the film surface, akin to a zone refinement. Further control over the size and separation distance of the domains can be achieved with cosolvents.
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Citations
Cited by
Mesoporous carbon materials: Synthesis and modification
Liang, C., Li, Z., & Dai, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702046 · Cited by 1,935
Block copolymer based nanostructures: Materials, processes, and applications to electronics
Kim, H.-C., Park, S.-M., & Hinsberg, W. D. (2010) · Chemical Reviews · doi:10.1021/cr900159v · Cited by 1,017
Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers
Liang, C., Hong, K., Guiochon, G. A., Mays, J. W., & Dai, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200461051 · Cited by 834
Macroscopic 10-terabit–per–square-inch arrays from block copolymers with lateral order
Park, S., Lee, D. H., Xu, J., Kim, B., Hong, S. W., Jeong, U., Xu, T., & Russell, T. P. (2009) · Science · doi:10.1126/science.1168108 · Cited by 740
Self-citationEvolution of Block Copolymer Lithography to Highly Ordered Square Arrays
Tang, C., Lennon, E. M., Fredrickson, G. H., Kramer, E. J., & Hawker, C. J. (2008) · Science · doi:10.1126/science.1162950 · Cited by 624
Metadata
- Authors
- Kim, S. H., Misner, M. J., Xu, T., Kimura, M., & Russell, T. P.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2004-02-03
- Volume
- 16
- Issue
- 3
- Pages
- 226-231
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2077379822
- Cited by
- 922
- References
- 0
- FWCI
- 25.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kim, S. H., Misner, M. J., Xu, T., Kimura, M., & Russell, T. P. (2004). Highly Oriented and Ordered Arrays from Block Copolymers via Solvent Evaporation. Advanced Materials. https://doi.org/10.1002/adma.200304906
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
