Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers
Open accessAbstract
Made to order: The synthesis of well-defined porous carbon films involves four steps: 1) monomer–block copolymer film casting, 2) structure refining through solvent annealing, 3) polymerization of the carbon precursor, and 4) carbonization. The resulting films, such as that depicted, have potential as separation membranes, chemical sensors, and catalysts.
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Synthesized BCPs for templating usually contain P2VP, P4VP, or PEO as the hydrophilic block, and PS, PMMA, PI, PIB, and PAN as the hydrophobic block.
“These synthesized BCPs usually contain poly(2-vinylpyridine) (P2VP), poly(4-vinylpyridine) (P4VP), or poly(ethylene oxide) (PEO) as the hydrophilic block, and PS, PMMA, PI, polyisobutylene (PIB), and polyacrylonitrile (PAN) as the hydrophobic block [143,144].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [144]
The Nanoporous Films section describes PS-P4VP as a block-copolymer template, with resorcinol selectively associating with the P4VP domain. This supports PS and P4VP as an example, but the paper does not establish that the listed blocks are usually used or discuss the other listed polymers. (LLM, conf=0.86)
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“These synthesized BCPs usually contain poly(2-vinylpyridine) (P2VP), poly(4-vinylpyridine) (P4VP), or poly(ethylene oxide) (PEO) as the hydrophilic block, and PS, PMMA, PI, polyisobutylene (PIB), and polyacrylonitrile (PAN) as the hydrophobic block [143,144].”
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- Authors
- Liang, C., Hong, K., Guiochon, G. A., Mays, J. W., & Dai, S.
- Affiliations
- Oak Ridge National Laboratory (US)
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-11-02
- Volume
- 43
- Issue
- 43
- Pages
- 5785-5789
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2156517468
- Cited by
- 834
- References
- 30
- Citations by year
- 2026: 9 · 2025: 16 · 2024: 16 · 2023: 30 · 2022: 34 · 2021: 30 · 2020: 39 · 2019: 37 · 2018: 46 · 2017: 52 · 2016: 52 · 2015: 60 · 2014: 65 · 2013: 61 · 2012: 54
- FWCI
- 9.36
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- U.S. Department of Energy (AC05-00OR22725, DE--AC05--00OR22725, DE-AC05?, 00OR22725)
- Battelle (DE-AC05- 00OR22725, AC05-00OR22725, DE-AC05)
- UT-Battelle (DE-AC05, AC05-00OR22725)
- Basic Energy Sciences (AC0500OR22725, DEAC05-00OR22725)
- Oak Ridge National Laboratory (AC05-00OR22725, DE-AC05-00OR22725)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- porous carbon films, block copolymer self-assembly, block copolymer films, solvent annealing, carbonization, separation membranes, chemical sensors, catalyst supports
- MeSH terms
- Kinetics, Manufactured Materials, Microscopy, Electron, Polymers, Surface Properties, Porosity, Spectroscopy, Fourier Transform Infrared, Nanotechnology, Nanotubes, Carbon
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