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New Transparent Methylsilsesquioxane Aerogels and Xerogels with Improved Mechanical Properties
Abstract
Transparent organic–inorganic hybrid aerogels and xerogels are prepared by using a sol–gel synthesis from a single trifunctional precursor, methyltrimethoxysilane (see figure). Obtained aerogels show a reversible shrinkage–recovery response against uniaxial compression. Aerogel-like xerogels are successfully obtained by evaporation drying under ambient pressure because the gels recover from the temporal shrinkage caused by the capillary force of a drying solvent. Pore properties and nanotextures are well-preserved in the resultant xerogels.
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Citations
Cited by
An Overview on Silica Aerogels Synthesis and Different Mechanical Reinforcing Strategies
Maleki, H., Durães, L., & Portugal, A. (2014) · Journal of Non-Crystalline Solids · doi:10.1016/j.jnoncrysol.2013.10.017 · Cited by 740
Tailoring Mechanical Properties of Aerogels for Aerospace Applications
Randall, J. P., Meador, M. A. B., & Jana, S. C. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am200007n · Cited by 579
Parale, V. G., Kim, T., Choi, H., Phadtare, V. D., Dhavale, R. P., Kanamori, K., & Park, H. (2024) · Advanced Materials · doi:10.1002/adma.202307772 · Cited by 146
Self-citationFlexible and Transparent Silica Aerogels: An Overview
Parale, V. G., Lee, K.-Y., & Park, H.-H. (2017) · Journal of the Korean Ceramic Society · doi:10.4191/kcers.2017.54.3.12 · Cited by 113
Silica Centered Aerogels as Advanced Functional Material and Their Applications: A Review
Ahmad, S., Ahmad, S., & Sheikh, J. N. (2023) · Journal of Non-Crystalline Solids · doi:10.1016/j.jnoncrysol.2023.122322 · Cited by 97
Metadata
- Authors
- Kanamori, K., Aizawa, M., Nakanishi, K., & Hanada, T.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2007-05-15
- Volume
- 19
- Issue
- 12
- Pages
- 1589-1593
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2048807294
- Cited by
- 447
- References
- 0
- FWCI
- 3.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kanamori, K., Aizawa, M., Nakanishi, K., & Hanada, T. (2007). New Transparent Methylsilsesquioxane Aerogels and Xerogels with Improved Mechanical Properties. Advanced Materials. https://doi.org/10.1002/adma.200602457
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
