Edge‐Oriented MoS 2 Nanoporous Films as Flexible Electrodes for Hydrogen Evolution Reactions and Supercapacitor Devices
Abstract
A simple method to fabricate edge-oriented MoS2 films with sponge-like morphologies is demonstrated. They are directly fabricated through the reaction of sulfur vapor with anodically formed Mo oxide sponge-like films on flexible Mo substrates. The edge-oriented MoS2 film delivers excellent hydrogen evolution reaction (HER) activity with enhanced kinetics and long-term cycling stability. The material also has superior energy-storage performance when working as a flexible, all-solid-state supercapacitor device.
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The XPS spectrum of S 2p shows two peaks at ~163.5 and ~162.3 eV corresponding to S2+ with p spin-orbit splitting, indicating the existence of MoS2 phase.
“Moreover, the two peaks at binding energies of ~163.5 and ~162.3 eV correspond to S 2+ with the p spin-orbit splitting, indicating the existence of MoS 2 phase [33,44,48,57].”
The XPS spectrum of Mo 3d shows a doublet at ~229.4 eV (Mo4+ 2d5/2) and ~232.6 eV (Mo4+ 2d3/2).
“First, the Mo 3d doublet is clearly observed at ~229.4 eV (Mo 4+ 2d 5/2 ) and at ~232.6 eV (Mo 4+ 2d 3/2 ) [33,44,48,56,57].”
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- Authors
- Yang, Y., Fei, H., Ruan, G., Xiang, C., & Tour, J. M.
- Affiliations
- Rice University (US)
- Corresponding author
- Tour, James M.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2014-10-29
- Volume
- 26
- Issue
- 48
- Pages
- 8163-8168
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2017305999
- Cited by
- 601
- References
- 17
- Citations by year
- 2026: 11 · 2025: 16 · 2024: 24 · 2023: 28 · 2022: 36 · 2021: 49 · 2020: 59 · 2019: 94 · 2018: 68 · 2017: 91 · 2016: 78 · 2015: 46 · 2014: 1
- FWCI
- 23.72
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Multidisciplinary University Research Initiative
- Air Force Office of Scientific Research
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Keywords
- MoS2, nanoporous films, flexible electrodes, hydrogen evolution reaction, supercapacitors, anodic aluminum oxide templates, sponge morphology, all-solid-state supercapacitors, energy storage
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