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Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host
Abstract
Direct evidence of Mg2+ intercalation into a spinel-type Mn2O4 is provided. By combining tools with different sensitivities, from atomic-resolution X-ray spectroscopy to bulk X-ray diffraction, it is demonstrated that Mg2+ reversibly occupies the tetrahedral sites of the spinel structure through the reduction of Mn when the electrochemical reaction is performed.
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Cites
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
Jain, A., Ong, S. P., Hautier, G., Chen, W., Richards, W. D., Dacek, S., Cholia, S., Gunter, D., Skinner, D., Ceder, G., et al. (2013) · APL Materials · doi:10.1063/1.4812323 · Cited by 13,094
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis
Ong, S. P., Richards, W. D., Jain, A., Hautier, G., Kocher, M., Cholia, S., Gunter, D., Chevrier, V. L., Persson, K. A., & Ceder, G. (2013) · Computational Materials Science · doi:10.1016/j.commatsci.2012.10.028 · Cited by 4,534
Thackeray, M. M., Wolverton, C., & Isaacs, E. D. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21892e · Cited by 2,515
The rechargeable revolution: a better battery
Van Noorden, R. (2014) · Nature · doi:10.1038/507026a · Cited by 1,047
Cited by
Zhang, N., Cheng, F., Liu, Y., Zhao, Q., Lei, K., Chen, C., Liu, X., & Chen, J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05958 · Cited by 1,886
Tian, Y., Zeng, G., Rutt, A., Shi, T., Kim, H., Wang, J., Koettgen, J., Sun, Y., Ouyang, B., Chen, T., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00767 · Cited by 1,614
Yan, M., He, P., Chen, Y., Wang, S., Wei, Q., Zhao, K., Xu, X., An, Q., Shuang, Y., Shao, Y., et al. (2018) · Advanced Materials · doi:10.1002/adma.201703725 · Cited by 1,456
Single-Atom Catalysts across the Periodic Table
Kaiser, S. K., Chen, Z., Faust Akl, D., Mitchell, S., & Pérez-Ramírez, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00576 · Cited by 1,367
Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
Canepa, P., Sai Gautam, G., Hannah, D. C., Malik, R., Liu, M., Gallagher, K. G., Persson, K. A., & Ceder, G. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00614 · Cited by 1,159
Metadata
- Authors
- Kim, C., Phillips, P. J., Key, B., Yi, T., Nordlund, D., Yu, Y., Bayliss, R. D., Han, S., He, M., Zhang, Z., Burrell, A. K., Klie, R. F., & Cabana, J.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2015-04-17
- Volume
- 27
- Issue
- 22
- Pages
- 3377-3384
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2088898480
- Cited by
- 200
- References
- 4
- FWCI
- 11.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kim, C., Phillips, P. J., Key, B., Yi, T., Nordlund, D., Yu, Y., Bayliss, R. D., Han, S., He, M., Zhang, Z., Burrell, A. K., Klie, R. F., & Cabana, J. (2015). Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host. Advanced Materials. https://doi.org/10.1002/adma.201500083
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