Recent Strategies for Improving the Catalytic Activity of 2D TMD Nanosheets Toward the Hydrogen Evolution Reaction
Abstract
Two-dimensional (2D) transition-metal dichalcogenide (TMD) nanosheets have emerged as a fascinating new class of materials for catalysis. These nanosheets are active for several important catalysis reactions including hydrogen evolution from water. The rich chemistry of TMDs combined with numerous strategies that allow tuning of their electronic properties make these materials very attractive for understanding the fundamental principles of electro- and photocatalysis, as well as for developing highly efficient, renewable, and affordable catalysts for large-scale production of hydrogen. Recent developments are highlighted and important challenges in using TMDs as catalysts are also discussed.
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Ultrathin architecture of TMD is favorable for exposing edge active sites to catalyze HER.
“The ultrathin architecture of TMD is favorable for exposing those active sites located on edges to catalyze HER.”
From Carbon-Nanotube-Incorporated Graphene Scroll-Sheet Conjoined Aerogels for Efficient Hydrogen Evolution Reaction (2017) · cites this paper as [6]
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169 · see citing works
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034 · see citing works
Self-citationJaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100 · see citing works
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001 · see citing works
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097 · see citing works
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234 · see citing works
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641 · see citing works
Self-citationXie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350 · see citing works
Synthesis of MoS <sub>2</sub> and MoSe <sub>2</sub> Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250 · see citing works
Quantum spin Hall effect in two-dimensional transition metal dichalcogenides
Qian, X., Liu, J., Fu, L., & Li, J. (2014) · Science · doi:10.1126/science.1256815 · Cited by 2,053 · see citing works
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153 · see citing works
Tuning the MoS <sub>2</sub> Edge-Site Activity for Hydrogen Evolution via Support Interactions
Tsai, C., Abild-Pedersen, F., & Nørskov, J. K. (2014) · Nano Letters · doi:10.1021/nl404444k · Cited by 760 · see citing works
Layer-Dependent Electrocatalysis of MoS<sub>2</sub> for Hydrogen Evolution
Yu, Y., Huang, S.-Y., Li, Y., Steinmann, S. N., Yang, W., & Cao, L. (2014) · Nano Letters · doi:10.1021/nl403620g · Cited by 740 · see citing works
Seger, B., Laursen, A. B., Vesborg, P. C. K., Pedersen, T., Hansen, O., Dahl, S., & Chorkendorff, I. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203585 · Cited by 306 · see citing works
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Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133 · see citing works
Support and Interface Effects in Water‐Splitting Electrocatalysts
Zhang, J., Zhang, Q., & Feng, X. (2019) · Advanced Materials · doi:10.1002/adma.201808167 · Cited by 916 · see citing works
2D Transition Metal Dichalcogenides-Based Electrocatalysts for Hydrogen Evolution Reaction
Mondal, A., & Vomiero, A. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202208994 · Cited by 295 · see citing works
3D Mesoporous van der Waals Heterostructures for Trifunctional Energy Electrocatalysis
Tang, C., Zhong, L., Zhang, B., Wang, H., & Zhang, Q. (2018) · Advanced Materials · doi:10.1002/adma.201705110 · Cited by 218 · see citing works
Ali, A., & Shen, P. K. (2020) · Carbon Energy · doi:10.1002/cey2.26 · Cited by 199 · see citing works
Wang, C., Guo, W., Chen, T., Lu, W., Song, Z., Yan, C., Feng, Y., Gao, F., Zhang, X., Rao, Y., et al. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.215899 · Cited by 184 · see citing works
Layered transition metal dichalcogenide electrochemistry: journey across the periodic table
Chia, X., & Pumera, M. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00846e · Cited by 163 · see citing works
Li, G., Sun, T., Niu, H., Yan, Y., Liu, T., Jiang, S., Yang, Q., Zhou, W., & Guo, L. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202212514 · Cited by 130 · see citing works
Shi, Y., Gao, W., Lu, H., Huang, Y., Zuo, L., Fan, W., & Liu, T. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01181 · Cited by 49 · see citing works
- Authors
- Voiry, D., Yang, J., & Chhowalla, M.
- Affiliations
- Rutgers, The State University of New Jersey (US)
- Corresponding author
- Chhowalla, Manish
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2016-02-12
- Volume
- 28
- Issue
- 29
- Pages
- 6197-6206
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2265025560
- Cited by
- 949
- References
- 14
- Citations by year
- 2026: 51 · 2025: 48 · 2024: 77 · 2023: 77 · 2022: 97 · 2021: 91 · 2020: 127 · 2019: 123 · 2018: 125 · 2017: 105 · 2016: 27
- FWCI
- 34.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- National Sleep Foundation (DGE 0903661, ECCS 1128335)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- transition metal dichalcogenides, nanosheets, hydrogen evolution reaction, electrocatalysis, photocatalysis, hydrogen production, catalyst design, electronic properties tuning
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