The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Nickel–Cobalt Diselenide 3D Mesoporous Nanosheet Networks Supported on Ni Foam: An All‐pH Highly Efficient Integrated Electrocatalyst for Hydrogen Evolution
Abstract
Novel 3D Ni 1−xCoxSe 2 mesoporous nanosheet networks with tunable stoichiometry are successfully synthesized on Ni foam (Ni 1−xCoxSe 2 MNSN/NF with x ranging from 0 to 0.35). The collective effects of special morphological design and electronic structure engineering enable the integrated electrocatalyst to have very high activity for hydrogen evolution reaction (HER) and excellent stability in a wide pH range. Ni 0.89 Co 0.11 Se 2 MNSN/NF is revealed to exhibit an overpotential (η 10) of 85 mV at −10 mA cm−2 in alkaline medium (pH 14) and η 10 of 52 mV in acidic solution (pH 0), which are the best among all selenide‐based electrocatalysts reported thus far. In particular, it is shown for the first time that the catalyst can work efficiently in neutral solution (pH 7) with a record η 10 of 82 mV for all noble metal‐free electrocatalysts ever reported. Based on theoretical calculations, it is further verified that the advanced all‐pH HER activity of Ni 0.89 Co 0.11 Se 2 is originated from the enhanced adsorption of both H+ and H 2 O induced by the substitutional doping of cobalt at an optimal level. It is believed that the present work provides a valuable route for the design and synthesis of inexpensive and efficient all‐pH HER electrocatalysts.
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Cites
Noble metal-free hydrogen evolution catalysts for water splitting
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
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Hydrogen evolution by a metal-free electrocatalyst
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Cited by
Anantharaj, S., Ede, S. R., Karthick, K., Sam Sankar, S., Sangeetha, K., Karthik, P. E., & Kundu, S. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03457a · Cited by 1,632
Zhang, H., Li, X., Hähnel, A., Naumann, V., Lin, C., Azimi, S., Schweizer, S. L., Maijenburg, A. W., & Wehrspohn, R. B. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706847 · Cited by 917
Jiang, K., Liu, B., Luo, M., Ning, S., Peng, M., Zhao, Y., Lu, Y.-R., Chan, T.-S., de Groot, F. M. F., & Tan, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-09765-y · Cited by 670
Self-citationZhou, Z., Pei, Z., Wei, L., Zhao, S., Jian, X., & Chen, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01856b · Cited by 542
Self-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Metadata
- Authors
- Liu, B., Zhao, Y., Peng, H., Zhang, Z., Sit, C., Yuen, M., Zhang, T., Lee, C., & Zhang, W.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-03-06
- Volume
- 29
- Issue
- 19
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2594888243
- Cited by
- 463
- References
- 17
- FWCI
- 19.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, B., Zhao, Y., Peng, H., Zhang, Z., Sit, C., Yuen, M., Zhang, T., Lee, C., & Zhang, W. (2017). Nickel–Cobalt Diselenide 3D Mesoporous Nanosheet Networks Supported on Ni Foam: An All‐pH Highly Efficient Integrated Electrocatalyst for Hydrogen Evolution. Advanced Materials. https://doi.org/10.1002/adma.201606521
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