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Cited by 475

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Direct Synthesis of Large‐Area 2D Mo2C on In Situ Grown Graphene

Geng, Dechao, Zhao, Xiaoxu, Chen, Zhongxin, Sun, Weiwei, Fu, Wei, Chen, Jianyi, Liu, Wei, Zhou, Wu, Loh, Kian Ping·2017·Advanced Materials

Abstract

As a new member of the MXene group, 2D Mo 2 C has attracted considerable interest due to its potential application as electrodes for energy storage and catalysis. The large‐area synthesis of Mo 2 C film is needed for such applications. Here, the one‐step direct synthesis of 2D Mo 2 C‐on‐graphene film by molten copper‐catalyzed chemical vapor deposition (CVD) is reported. High‐quality and uniform Mo 2 C film in the centimeter range can be grown on graphene using a Mo–Cu alloy catalyst. Within the vertical heterostructure, graphene acts as a diffusion barrier to the phase‐segregated Mo and allows nanometer‐thin Mo 2 C to be grown. Graphene‐templated growth of Mo 2 C produces well‐faceted, large‐sized single crystals with low defect density, as confirmed by scanning transmission electron microscopy (STEM) measurements. Due to its more efficient graphene‐mediated charge‐transfer kinetics, the as‐grown Mo 2 C‐on‐graphene heterostructure shows a much lower onset voltage for hydrogen evolution reactions as compared to Mo 2 C‐only electrodes.

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Metadata

Authors
Geng, D., Zhao, X., Chen, Z., Sun, W., Fu, W., Chen, J., Liu, W., Zhou, W., & Loh, K. P.
Venue
Advanced Materials
Publisher
Wiley
Published
2017-07-19
Volume
29
Issue
35
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2738580821
Cited by
475
References
3
FWCI
12.65
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Direct Synthesis of Large‐Area 2D Mo2C on In Situ Grown Graphene. https://app.cochat.ai/papers/10.1002/adma.201700072
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Geng, D., Zhao, X., Chen, Z., Sun, W., Fu, W., Chen, J., Liu, W., Zhou, W., & Loh, K. P. (2017). Direct Synthesis of Large‐Area 2D Mo2C on In Situ Grown Graphene. Advanced Materials. https://doi.org/10.1002/adma.201700072

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