The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.
Bifunctional Transition Metal Hydroxysulfides: Room‐Temperature Sulfurization and Their Applications in Zn–Air Batteries
Abstract
Bifunctional electrocatalysis for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) constitutes the bottleneck of various sustainable energy devices and systems like rechargeable metal–air batteries. Emerging catalyst materials are strongly requested toward superior electrocatalytic activities and practical applications. In this study, transition metal hydroxysulfides are presented as bifunctional OER/ORR electrocatalysts for Zn–air batteries. By simply immersing Co‐based hydroxide precursor into solution with high‐concentration S 2−, transition metal hydroxides convert to hydroxysulfides with excellent morphology preservation at room temperature. The as‐obtained Co‐based metal hydroxysulfides are with high intrinsic reactivity and electrical conductivity. The electron structure of the active sites is adjusted by anion modulation. The potential for 10 mA cm−2 OER current density is 1.588 V versus reversible hydrogen electrode (RHE), and the ORR half‐wave potential is 0.721 V versus RHE, with a potential gap of 0.867 V for bifunctional oxygen electrocatalysis. The Co 3 FeS 1.5(OH)6 hydroxysulfides are employed in the air electrode for a rechargeable Zn–air battery with a small overpotential of 0.86 V at 20.0 mA cm−2, a high specific capacity of 898 mAh g−1, and a long cycling life, which is much better than Pt and Ir‐based electrocatalyst in Zn–air batteries.
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Cites
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
Cheng, F., & Chen, J. (2012) · Chemical Society Reviews · doi:10.1039/c1cs15228a · Cited by 2,677
Recent Progress in Cobalt‐Based Heterogeneous Catalysts for Electrochemical Water Splitting
Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Recent advances in zinc–air batteries
Li, Y., & Dai, H. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00015c · Cited by 2,315
Burke, M. S., Kast, M. G., Trotochaud, L., Smith, A. M., & Boettcher, S. W. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00281 · Cited by 1,972
Jiang, W.-J., Gu, L., Li, L., Zhang, Y., Zhang, X., Zhang, L.-J., Wang, J.-Q., Hu, J.-S., Wei, Z., & Wan, L.-J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00757 · Cited by 1,765
Electrically Rechargeable Zinc–Air Batteries: Progress, Challenges, and Perspectives
Fu, J., Cano, Z. P., Park, M. G., Yu, A., Fowler, M., & Chen, Z. (2017) · Advanced Materials · doi:10.1002/adma.201604685 · Cited by 1,594
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
Gorlin, Y., & Jaramillo, T. F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja104587v · Cited by 1,566
Cited by
A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions
Cui, X., Tang, C., & Zhang, Q. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201800369 · Cited by 1,314
Self-citationAdvanced Carbon for Flexible and Wearable Electronics
Wang, C., Xia, K., Wang, H., Liang, X., Yin, Z., & Zhang, Y. (2019) · Advanced Materials · doi:10.1002/adma.201801072 · Cited by 1,300
Self-citationAdvanced Architectures and Relatives of Air Electrodes in Zn–Air Batteries
Pan, J., Xu, Y. Y., Yang, H., Dong, Z., Liu, H., & Xia, B. Y. (2018) · Advanced Science · doi:10.1002/advs.201700691 · Cited by 848
Wang, H., Tang, C., & Zhang, Q. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803329 · Cited by 772
Self-citationSun, Y., Xue, Z., Liu, Q., Jia, Y., Li, Y., Liu, K., Lin, Y., Liu, M., Li, G., & Su, C.-Y. (2021) · Nature Communications · doi:10.1038/s41467-021-21595-5 · Cited by 687
Metadata
- Authors
- Wang, H., Tang, C., Wang, B., Li, B., & Zhang, Q.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-07-17
- Volume
- 29
- Issue
- 35
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2735083668
- Cited by
- 437
- References
- 64
- FWCI
- 15.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, H., Tang, C., Wang, B., Li, B., & Zhang, Q. (2017). Bifunctional Transition Metal Hydroxysulfides: Room‐Temperature Sulfurization and Their Applications in Zn–Air Batteries. Advanced Materials. https://doi.org/10.1002/adma.201702327
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