The DOI matches its Crossref record; 68 of the 68 references it cites were found in a registry or an index.
Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution
Open accessAbstract
Developing high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu 0.13 -BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu 0.13 -BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36 mV at a current density of 10 mA cm −2 in 1 M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H 2 O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design.
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Cited by
Rational Design of Better Hydrogen Evolution Electrocatalysts for Water Splitting: A Review
Liu, F., Shi, C., Guo, X., He, Z., Pan, L., Huang, Z., Zhang, X., & Zou, J. (2022) · Advanced Science · doi:10.1002/advs.202200307 · Cited by 455
Recent progress on the long‐term stability of hydrogen evolution reaction electrocatalysts
Zhai, W., Ma, Y., Chen, D., Ho, J. C., Dai, Z., & Qu, Y. (2022) · InfoMat · doi:10.1002/inf2.12357 · Cited by 375
Supports promote single-atom catalysts toward advanced electrocatalysis
Xu, H., Zhao, Y., Wang, Q., He, G., & Chen, H. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.214261 · Cited by 363
Deng, L., Hu, F., Ma, M., Huang, S., Xiong, Y., Chen, H., Li, L., & Peng, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202110374 · Cited by 331
Engineering Ruthenium-Based Electrocatalysts for Effective Hydrogen Evolution Reaction
Yang, Y., Yu, Y., Li, J., Chen, Q., Du, Y., Rao, P., Li, R., Jia, C., Kang, Z., Deng, P., et al. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00679-3 · Cited by 313
Metadata
- Authors
- Sun, Y., Xue, Z., Liu, Q., Jia, Y., Li, Y., Liu, K., Lin, Y., Liu, M., Li, G., & Su, C.-Y.
- Venue
- Nature Communications
- Published
- 2021-03-01
- Volume
- 12
- Issue
- 1
- Pages
- 1369-1369
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3135841876
- Cited by
- 687
- References
- 68
- FWCI
- 22.35
- Type
- journal article
- Language
- en
- Open access
- gold
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- Sun, Y., Xue, Z., Liu, Q., Jia, Y., Li, Y., Liu, K., Lin, Y., Liu, M., Li, G., & Su, C.-Y. (2021). Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution. Nature Communications. https://doi.org/10.1038/s41467-021-21595-5
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