The DOI matches its Crossref record; 57 of the 57 references it cites were found in a registry or an index.
Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition
Abstract
Lithium metal batteries (such as lithium–sulfur, lithium–air, solid state batteries with lithium metal anode) are highly considered as promising candidates for next‐generation energy storage systems. However, the unstable interfaces between lithium anode and electrolyte definitely induce the undesired and uncontrollable growth of lithium dendrites, which results in the short‐circuit and thermal runaway of the rechargeable batteries. Herein, a dual‐layered film is built on a Li metal anode by the immersion of lithium plates into the fluoroethylene carbonate solvent. The ionic conductive film exhibits a compact dual‐layered feature with organic components (ROCO 2 Li and ROLi) on the top and abundant inorganic components (Li 2 CO 3 and LiF) in the bottom. The dual‐layered interface can protect the Li metal anode from the corrosion of electrolytes and regulate the uniform deposition of Li to achieve a dendrite‐free Li metal anode. This work demonstrates the concept of rational construction of dual‐layered structured interfaces for safe rechargeable batteries through facile surface modification of Li metal anodes. This not only is critically helpful to comprehensively understand the functional mechanism of fluoroethylene carbonate but also affords a facile and efficient method to protect Li metal anodes.
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Cites
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Self-citationPromise and reality of post-lithium-ion batteries with high energy densities
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Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
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Self-citationNegating interfacial impedance in garnet-based solid-state Li metal batteries
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Cited by
Materials Design for Rechargeable Metal-Air Batteries
Wang, H.-F., & Xu, Q. (2019) · Matter · doi:10.1016/j.matt.2019.05.008 · Cited by 580
Lithium metal anodes: Present and future
Wang, R., Cui, W., Chu, F., & Wu, F. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.12.024 · Cited by 544
A robust all-organic protective layer towards ultrahigh-rate and large-capacity Li metal anodes
Li, S., Huang, J., Cui, Y., Liu, S., Chen, Z., Huang, W., Li, C., Liu, R., Fu, R., & Wu, D. (2022) · Nature Nanotechnology · doi:10.1038/s41565-022-01107-2 · Cited by 380
Self-citationWang, Z., Sun, Z., Shi, Y., Qi, F., Gao, X., Yang, H., Cheng, H., & Li, F. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100935 · Cited by 202
Metadata
- Authors
- Yan, C., Cheng, X., Tian, Y., Chen, X., Zhang, X., Li, W., Huang, J., & Zhang, Q.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-04-20
- Volume
- 30
- Issue
- 25
- Pages
- e1707629-e1707629
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2802466811
- Cited by
- 513
- References
- 57
- FWCI
- 25.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yan, C., Cheng, X., Tian, Y., Chen, X., Zhang, X., Li, W., Huang, J., & Zhang, Q. (2018). Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition. Advanced Materials. https://doi.org/10.1002/adma.201707629
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