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Ultrafast Zn2+ Intercalation and Deintercalation in Vanadium Dioxide

Ding, Junwei, Du, Zhiguo, Gu, Linqing, Li, Bin, Wang, Lizhen, Wang, Shiwen, Gong, Yongji, Yang, Shubin·2018·Advanced Materials

Abstract

Although rechargeable aqueous zinc‐ion batteries have attracted extensive interest due to their environmental friendliness and low cost, they still lack suitable cathodes with high rate capabilities, which are hampered by the intense charge repulsion of bivalent Zn 2+. Here, a novel intercalation pseudocapacitance behavior and ultrafast kinetics of Zn 2+ into the unique tunnels of VO 2 (B) nanofibers in aqueous electrolyte are demonstrated via in situ X‐ray diffraction and various electrochemical measurements. Because VO 2 (B) nanofibers possess unique tunnel transport pathways with big sizes (0.82 and 0.5 nm 2 along the b‐ and c‐axes) and little structural change on Zn 2+ intercalation, the limitation from solid‐state diffusion in the vanadium dioxide electrode is eliminated. Thus, VO 2 (B) nanofibers exhibit a high reversible capacity of 357 mAh g−1, excellent rate capability (171 mAh g−1 at 300 C), and high energy and power densities as applied for zinc‐ion storage.

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Metadata

Authors
Ding, J., Du, Z., Gu, L., Li, B., Wang, L., Wang, S., Gong, Y., & Yang, S.
Venue
Advanced Materials
Publisher
Wiley
Published
2018-05-15
Volume
30
Issue
26
Pages
e1800762-e1800762
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2804626698
Cited by
677
References
24
FWCI
28.88
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultrafast Zn2+ Intercalation and Deintercalation in Vanadium Dioxide. https://app.cochat.ai/papers/10.1002/adma.201800762
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Ding, J., Du, Z., Gu, L., Li, B., Wang, L., Wang, S., Gong, Y., & Yang, S. (2018). Ultrafast Zn2+ Intercalation and Deintercalation in Vanadium Dioxide. Advanced Materials. https://doi.org/10.1002/adma.201800762

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