The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Trifunctional Self‐Supporting Cobalt‐Embedded Carbon Nanotube Films for ORR, OER, and HER Triggered by Solid Diffusion from Bulk Metal
Abstract
The development of robust and efficient trifunctional catalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen reaction (HER) is central to regenerative metal–air batteries and overall water splitting. It is still a big challenge to achieve an efficient integration of three functions in one freestanding electrode. Herein, a facile and upscalable strategy is demonstrated, to construct cobalt nanoparticle‐encapsulated 3D conductive films (Co/CNFs), which were induced by in situ solid diffusion from bulk cobalt metal. Under high‐temperature, volatile cobalt species from bulk cobalt foil are trapped by the contacted nitrogen‐rich carbons, followed by catalytic growth of interconnected carbon tubes, forming the 3D structured film. This resulting film can be directly preformed as self‐supporting and binder‐free electrode, which simultaneously facilitates the ORR, OER, and HER with excellent activities and superior stability. Furthermore, such “all‐in‐one” film also exhibits remarkable performance for Zn–air batteries and overall water splitting, demonstrating its feasibility for practical applications.
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Cites
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
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Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Recent advances in zinc–air batteries
Li, Y., & Dai, H. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00015c · Cited by 2,315
Self-citationSingle Cobalt Atoms with Precise N‐Coordination as Superior Oxygen Reduction Reaction Catalysts
Yin, P., Yao, T., Wu, Y., Zheng, L., Lin, Y., Liu, W., Ju, H., Zhu, J., Hong, X., Deng, Z., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604802 · Cited by 2,251
Self-citationHigh-performance transition metal–doped Pt 3 Ni octahedra for oxygen reduction reaction
Huang, X., Zhao, Z., Cao, L., Chen, Y., Zhu, E., Lin, Z., Li, M., Yan, A., Zettl, A., Wang, Y. M., et al. (2015) · Science · doi:10.1126/science.aaa8765 · Cited by 1,898
Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells
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Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction
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Self-citationAdvances in understanding mechanisms underpinning lithium–air batteries
Aurbach, D., McCloskey, B. D., Nazar, L. F., & Bruce, P. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.128 · Cited by 1,254
Cited by
Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Diao, J., Qiu, Y., Liu, S., Wang, W., Chen, K., Li, H., Yuan, W., Qu, Y., & Guo, X. (2020) · Advanced Materials · doi:10.1002/adma.201905679 · Cited by 555
Self-citationRecent progress on the long‐term stability of hydrogen evolution reaction electrocatalysts
Zhai, W., Ma, Y., Chen, D., Ho, J. C., Dai, Z., & Qu, Y. (2022) · InfoMat · doi:10.1002/inf2.12357 · Cited by 375
Self-citationRecent Progress in Electrocatalysts for Acidic Water Oxidation
Lei, Z., Wang, T., Zhao, B., Cai, W., Liu, Y., Jiao, S., Li, Q., Cao, R., & Liu, M. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000478 · Cited by 336
Densely Isolated FeN4 Sites for Peroxidase Mimicking
Jiao, L., Wu, J., Zhong, H., Zhang, Y., Xu, W., Wu, Y., Chen, Y., Yan, H., Zhang, Q., Gu, W., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01647 · Cited by 312
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Metadata
- Authors
- Yang, Z., Zhao, C., Qu, Y., Zhou, H., Zhou, F., Wang, J., Wu, Y., & Li, Y.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-02-05
- Volume
- 31
- Issue
- 12
- Pages
- e1808043-e1808043
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2914053399
- Cited by
- 429
- References
- 32
- FWCI
- 13.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, Z., Zhao, C., Qu, Y., Zhou, H., Zhou, F., Wang, J., Wu, Y., & Li, Y. (2019). Trifunctional Self‐Supporting Cobalt‐Embedded Carbon Nanotube Films for ORR, OER, and HER Triggered by Solid Diffusion from Bulk Metal. Advanced Materials. https://doi.org/10.1002/adma.201808043
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