The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Intrinsic Carbon‐Defect‐Driven Electrocatalytic Reduction of Carbon Dioxide
Abstract
Heteroatom‐doped carbon catalysts are currently attracting enormous attention due to their excellent performance for the electrocatalytic carbon dioxide reduction reaction (ECRR). However, the origin of the high catalytic activities of doped‐carbon materials remains obscure with the role of intrinsic carbon defects in promoting the ECRR receiving little attention despite the abundance of carbon defects in all carbon‐based catalytic materials. Herein, a positive correlation is reported between the ECRR performance of carbon‐based catalysts and the content of intrinsic carbon defects contained within these catalysts. Further, it is demonstrated that defective porous carbon catalysts containing no active heteroatom dopants also show excellent catalytic performance for ECRR. C K‐edge near edge X‐ray absorption fine structure measurements and density functional theory calculations reveal that sp 2 defects (octagonal and pentagonal) rather than edge defects are key to the excellent ECRR activity of the defective porous carbon catalysts. This work thus makes an important contribution to the understanding of the origin of the ECRR activity of carbon‐based catalysts, with heteroatom doping perhaps being less important than previously envisaged for achieving a high ECRR performance.
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Hydrogen evolution by a metal-free electrocatalyst
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Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
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Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Insight into the design of defect electrocatalysts: From electronic structure to adsorption energy
Xie, C., Yan, D., Chen, W., Zou, Y., Chen, R., Zang, S., Wang, Y., Yao, X., & Wang, S. (2019) · Materials Today · doi:10.1016/j.mattod.2019.05.021 · Cited by 490
Defect engineering of two-dimensional materials for advanced energy conversion and storage
Liu, F., & Fan, Z. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00931e · Cited by 417
Effect of Intrinsic Defects of Carbon Materials on the Sodium Storage Performance
Guo, R., Lv, C., Xu, W., Sun, J., Zhu, Y., Yang, X., Li, J., Sun, J., Zhang, L., & Yang, D. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903652 · Cited by 369
Self-citationLi, X., Zhang, J., Huo, Y., Dai, K., Li, S., & Chen, S. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119452 · Cited by 367
Metadata
- Authors
- Wang, W., Shang, L., Chang, G., Yan, C., Shi, R., Zhao, Y., Waterhouse, G. I. N., Yang, D., & Zhang, T.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-03-28
- Volume
- 31
- Issue
- 19
- Pages
- e1808276-e1808276
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2925658181
- Cited by
- 431
- References
- 8
- FWCI
- 11.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, W., Shang, L., Chang, G., Yan, C., Shi, R., Zhao, Y., Waterhouse, G. I. N., Yang, D., & Zhang, T. (2019). Intrinsic Carbon‐Defect‐Driven Electrocatalytic Reduction of Carbon Dioxide. Advanced Materials. https://doi.org/10.1002/adma.201808276
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