Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Abstract
In view of the climate changes caused by the continuously rising levels of atmospheric CO 2 , advanced technologies associated with CO 2 conversion are highly desirable. In recent decades, electrochemical reduction of CO 2 has been extensively studied since it can reduce CO 2 to value‐added chemicals and fuels. Considering the sluggish reaction kinetics of the CO 2 molecule, efficient and robust electrocatalysts are required to promote this conversion reaction. Here, recent progress and opportunities in inorganic heterogeneous electrocatalysts for CO 2 reduction are discussed, from the viewpoint of both experimental and computational aspects. Based on elemental composition, the inorganic catalysts presented here are classified into four groups: metals, transition‐metal oxides, transition‐metal chalcogenides, and carbon‐based materials. However, despite encouraging accomplishments made in this area, substantial advances in CO 2 electrolysis are still needed to meet the criteria for practical applications. Therefore, in the last part, several promising strategies, including surface engineering, chemical modification, nanostructured catalysts, and composite materials, are proposed to facilitate the future development of CO 2 electroreduction.
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Pd has produced formate at low overpotentials, but CO poisoning of the catalyst has limited stable operation.
“In addition, Pd has produced formate at low overpotentials, but CO poisoning of the catalyst has limited stable operation.[73]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [73]
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- Authors
- Zhu, D. D., Liu, J. L., & Qiao, S. Z.
- Affiliations
- School of Chemical Engineering University of Adelaide Adelaide SA 5005 Australia
- The University of Adelaide (AU)
- Tianjin University (CN)
- Corresponding author
- Qiao, Shi Zhang
- ORCID
- Qiao, Shi Zhang
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2016-03-21
- Volume
- 28
- Issue
- 18
- Pages
- 3423-3452
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2297401062
- Cited by
- 1,594
- References
- 208
- Citations by year
- 2026: 82 · 2025: 111 · 2024: 168 · 2023: 170 · 2022: 183 · 2021: 225 · 2020: 202 · 2019: 197 · 2018: 165 · 2017: 82 · 2016: 9
- FWCI
- 41.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
- Funders
- Australian Research Council (DP130104459, DP140104062, DP1601048866)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, CO2 conversion, transition metal oxides, transition metal chalcogenides, metal catalysts, carbon materials, surface engineering, chemical modification, nanocatalysts, composite materials, CO2 electrolysis
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