Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2

Liang, Zhi-Qin; Zhuang, Tao-Tao; Seifitokaldani, Ali; Li, Jun; Huang, Chun-Wei; Tan, Chih-Shan; Li, Yi; De Luna, Phil; Dinh, Cao Thang; Hu, Yongfeng; Xiao, Qunfeng; Hsieh, Pei-Lun; Wang, Yuhang; Li, Fengwang; Quintero-Bermudez, Rafael; Zhou, Yansong; Chen, Peining; Pang, Yuanjie; Lo, Shen-Chuan; Chen, Lih-Juann; Tan, Hairen; Xu, Zheng; Zhao, Suling; Sinton, David; Sargent, Edward H.

doi:10.1038/s41467-018-06311-0

Cited by 393CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingAdvanced Photocatalysis Techniques

Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2

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Liang, Zhi-Qin, Zhuang, Tao-Tao, Seifitokaldani, Ali, Li, Jun, Huang, Chun-Wei, Tan, Chih-Shan, Li, Yi, De Luna, Phil +17 more·2018·Nature Communications

DOI 10.1038/s41467-018-06311-0PMC PMC6148248

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Abstract

Copper-based materials are promising electrocatalysts for CO 2 reduction. Prior studies show that the mixture of copper (I) and copper (0) at the catalyst surface enhances multi-carbon products from CO 2 reduction; however, the stable presence of copper (I) remains the subject of debate. Here we report a copper on copper (I) composite that stabilizes copper (I) during CO 2 reduction through the use of copper nitride as an underlying copper (I) species. We synthesize a copper-on-nitride catalyst that exhibits a Faradaic efficiency of 64 ± 2% for C 2+ products. We achieve a 40-fold enhancement in the ratio of C 2+ to the competing CH 4 compared to the case of pure copper. We further show that the copper-on-nitride catalyst performs stable CO 2 reduction over 30 h. Mechanistic studies suggest that the use of copper nitride contributes to reducing the CO dimerization energy barrier—a rate-limiting step in CO 2 reduction to multi-carbon products.

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By altering the reaction environment through increased electric fields, increased CO coverage, and/or increased catalyst strain, it is possible to improve the catalytic activity towards multi-carbon products.
“Thus, by altering the reaction environment through increased electric fields (e.g.larger cations in the electrolyte), increased CO coverage (e.g. higher CO2 pressure), and/or increased catalyst strain (e.g.engineering a core-shell structure [63] ) it is possible to improve the catalytic activity towards multi-carbon products.”
From Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [63]

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Metal–Oxide Interfaces for Selective Electrochemical C–C Coupling Reactions
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Lithiation‐Enabled High‐Density Nitrogen Vacancies Electrocatalyze CO2 to C2 Products
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In-situ reconstruction of catalysts in cathodic electrocatalysis: New insights into active-site structures and working mechanisms
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Efficient Hydrogenation of Methyl Palmitate to Hexadecanol over Cu/m-ZrO 2 Catalysts: Synergistic Effect of Cu Species and Oxygen Vacancies
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An MOF-derived copper@nitrogen-doped carbon composite: the synergistic effects of N-types and copper on selective CO 2 electroreduction
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Unveiling Electrochemical Urea Synthesis by Co‐Activation of CO 2 and N 2 with Mott–Schottky Heterostructure Catalysts
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Selective electrochemical CO 2 conversion to multicarbon alcohols on highly efficient N-doped porous carbon-supported Cu catalysts
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Structure-designed synthesis of hollow/porous cobalt sulfide/phosphide based materials for optimizing supercapacitor storage properties and hydrogen evolution reaction
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Surface engineering of Cu catalysts for electrochemical reduction of CO2 to value-added multi-carbon products
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Surface Reconstruction of Covellite CuS Nanocrystals for Enhanced OER Catalytic Performance in Alkaline Solution
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Linking the Dynamic Chemical State of Catalysts with the Product Profile of Electrocatalytic CO2 Reduction
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Ceo 2 /Cus Nanoplates Electroreduce Co 2 to Ethanol with Stabilized Cu + Species
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Gold-like activity copper-like selectivity of heteroatomic transition metal carbides for electrocatalytic carbon dioxide reduction reaction
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Ultralow Coordination Copper Sites Compartmentalized within Ordered Pores for Highly Efficient Electrosynthesis of n-Propanol from CO2
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High Efficient Catalyst of N‐doped Carbon Modified Copper Containing Rich Cu−N−C Active Sites for Electrocatalytic CO 2 Reduction
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Enhanced CO adsorption for electrochemical reduction of CO2 to multi-carbon products using Cu-enriched Cu3N films
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Selective Electroreduction of CO2 to C2 Products over Cu3N‐Derived Cu Nanowires
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Integrating Cu+/Cu0 sites on porous nitrogen-doped carbon nanofibers for stable and efficient CO2 electroreduction to multicarbon products
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Tailoring Microenvironments and In Situ Transformations of Cu Catalysts for Selective and Stable Electrosynthesis of Multicarbon Products
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Authors: Liang, Z.-Q., Zhuang, T.-T., Seifitokaldani, A., Li, J., Huang, C.-W., Tan, C.-S., Li, Y., De Luna, P., Dinh, C. T., Hu, Y., Xiao, Q., Hsieh, P.-L., Wang, Y., Li, F., Quintero-Bermudez, R., Zhou, Y., Chen, P., Pang, Y., Lo, S.-C., Chen, L.-J., Tan, H., Xu, Z., Zhao, S., Sinton, D., & Sargent, E. H.
Affiliations: University of Toronto (CA)
Industrial Technology Research Institute (TW)
University of Science and Technology of China (CN)
Canadian Light Source (Canada) (CA)
National Tsing Hua University (TW)
Beijing Jiaotong University (CN)
Corresponding author: Sargent, Edward H.
ORCID: Seifitokaldani, Ali
Li, Jun
Huang, Chun-Wei
Tan, Chih-Shan
Li, Yi
De Luna, Phil
Dinh, Cao Thang
Hu, Yongfeng
Xiao, Qunfeng
Wang, Yuhang
Li, Fengwang
Zhou, Yansong
Chen, Peining
Pang, Yuanjie
Chen, Lih-Juann
Tan, Hairen
Xu, Zheng
Zhao, Suling
Sinton, David
Sargent, Edward H.
Venue: Nature Communications
Publisher: Springer Science and Business Media LLC
Published: 2018-09-20
Volume: 9
Issue: 1
Pages: 3828-3828
ISSN: 2041-1723 (ISSN-L)
DOI: 10.1038/s41467-018-06311-0
PMC: PMC6148248
OpenAlex: W2889577864
Cited by: 393
References: 48
Citations by year: 2026: 22 · 2025: 48 · 2024: 62 · 2023: 64 · 2022: 58 · 2021: 59 · 2020: 54 · 2019: 25 · 2018: 1
FWCI: 8.03
Type: journal article
Language: en
Open access: gold
doi.org
Licence: cc-by
creativecommons.org/licenses/by/4.0 (tdm)
creativecommons.org/licenses/by/4.0 (vor)
Locations: Nature Communications (publishedVersion, cc-by)
Europe PMC (PubMed Central) (publishedVersion, cc-by)
PubMed Central (publishedVersion, cc-by)
PubMed (publishedVersion)
RePEc: Research Papers in Economics (submittedVersion)
DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders: Canadian Institute for Advanced Research
Canadian Light Source
University of Saskatchewan
Ontario Centres of Excellence
Nederlandse Organisatie voor Wetenschappelijk Onderzoek (680-50-1511, 680-50-151)
University of Toronto
Mitacs
China Scholarship Council
Beijing Jiaotong University
Canadian Institutes of Health Research
Natural Sciences and Engineering Research Council of Canada
Western Economic Diversification Canada
National Research Council Canada
Fonds de recherche du Québec – Nature et technologies
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
Keywords: CO2 reduction, copper electrocatalysts, copper nitride, multi-carbon products, Faradaic efficiency, CO dimerization, reaction mechanism, catalyst stability, methane selectivity

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Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2

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