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Cited by 358

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Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO2 Electroreduction

Lin, Long, Li, Haobo, Yan, Chengcheng, Li, Hefei, Si, Rui, Li, Mingrun, Xiao, Jianping, Wang, Guoxiong, Bao, Xinhe·2019·Advanced Materials

Abstract

Simultaneously achieving high Faradaic efficiency, current density, and stability at low overpotentials is essential for industrial applications of electrochemical CO 2 reduction reaction (CO 2 RR). However, great challenges still remain in this catalytic process. Herein, a synergistic catalysis strategy is presented to improve CO 2 RR performance by anchoring Fe‐N sites with cobalt phthalocyanine (denoted as CoPc©Fe‐N‐C). The potential window of CO Faradaic efficiency above 90% is significantly broadened from 0.18 V over Fe‐N‐C alone to 0.71 V over CoPc©Fe‐N‐C while the onset potential of CO 2 RR over both catalysts is as low as −0.13 V versus reversible hydrogen electrode. What is more, the maximum CO current density is increased ten times with significantly enhanced stability. Density functional theory calculations suggest that anchored cobalt phthalocyanine promotes the CO desorption and suppresses the competitive hydrogen evolution reaction over Fe‐N sites, while the *COOH formation remains almost unchanged, thus demonstrating unprecedented synergistic effect toward CO 2 RR.

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Metadata

Authors
Lin, L., Li, H., Yan, C., Li, H., Si, R., Li, M., Xiao, J., Wang, G., & Bao, X.
Venue
Advanced Materials
Publisher
Wiley
Published
2019-08-22
Volume
31
Issue
41
Pages
e1903470-e1903470
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2969763154
Cited by
358
References
5
FWCI
10.00
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO2 Electroreduction. https://app.cochat.ai/papers/10.1002/adma.201903470
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Lin, L., Li, H., Yan, C., Li, H., Si, R., Li, M., Xiao, J., Wang, G., & Bao, X. (2019). Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO2 Electroreduction. Advanced Materials. https://doi.org/10.1002/adma.201903470

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