The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO2 Electroreduction
Abstract
Simultaneously achieving high Faradaic efficiency, current density, and stability at low overpotentials is essential for industrial applications of electrochemical CO 2 reduction reaction (CO 2 RR). However, great challenges still remain in this catalytic process. Herein, a synergistic catalysis strategy is presented to improve CO 2 RR performance by anchoring Fe‐N sites with cobalt phthalocyanine (denoted as CoPc©Fe‐N‐C). The potential window of CO Faradaic efficiency above 90% is significantly broadened from 0.18 V over Fe‐N‐C alone to 0.71 V over CoPc©Fe‐N‐C while the onset potential of CO 2 RR over both catalysts is as low as −0.13 V versus reversible hydrogen electrode. What is more, the maximum CO current density is increased ten times with significantly enhanced stability. Density functional theory calculations suggest that anchored cobalt phthalocyanine promotes the CO desorption and suppresses the competitive hydrogen evolution reaction over Fe‐N sites, while the *COOH formation remains almost unchanged, thus demonstrating unprecedented synergistic effect toward CO 2 RR.
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Cites
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Trends in electrochemical CO2 reduction activity for open and close-packed metal surfaces
Shi, C., Hansen, H. A., Lausche, A. C., & Nørskov, J. K. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54822h · Cited by 465
Li, Y., Su, H., Chan, S. H., & Sun, Q. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01165 · Cited by 265
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Emerging Dual‐Atomic‐Site Catalysts for Efficient Energy Catalysis
Zhang, W., Chao, Y., Zhang, W., Zhou, J., Lv, F., Wang, K., Lin, F., Luo, H., Li, J., Tong, M., et al. (2021) · Advanced Materials · doi:10.1002/adma.202102576 · Cited by 528
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination
Lu, B., Liu, Q., & Chen, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01950 · Cited by 394
Pan, Y., Zhang, C., Liu, Z., Chen, C., & Li, Y. (2020) · Matter · doi:10.1016/j.matt.2019.11.014 · Cited by 341
Metadata
- Authors
- Lin, L., Li, H., Yan, C., Li, H., Si, R., Li, M., Xiao, J., Wang, G., & Bao, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-08-22
- Volume
- 31
- Issue
- 41
- Pages
- e1903470-e1903470
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2969763154
- Cited by
- 358
- References
- 5
- FWCI
- 10.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, L., Li, H., Yan, C., Li, H., Si, R., Li, M., Xiao, J., Wang, G., & Bao, X. (2019). Synergistic Catalysis over Iron‐Nitrogen Sites Anchored with Cobalt Phthalocyanine for Efficient CO2 Electroreduction. Advanced Materials. https://doi.org/10.1002/adma.201903470
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